Local compressive strain-induced anti-corrosion over isolated Ru-decorated Co3O4 for efficient acidic oxygen evolution

• Published in: Nature communications Vol. 15; no. 1; pp. 9514 - 14
• Main Authors: Zuo, Shouwei, Wu, Zhi-Peng, Xu, Deting, Ahmad, Rafia, Zheng, Lirong, Zhang, Jing, Zhao, Lina, Huang, Wenhuan, Al Qahtani, Hassan, Han, Yu, Cavallo, Luigi, Zhang, Huabin
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 04.11.2024; Nature Publishing Group; Nature Portfolio
• Subjects: 639/301/299/886; 639/4077/909/4085; 639/638/161/886; 639/638/77/886; Cobalt oxides; Compressive properties; Corrosion; Corrosion effects; Corrosion potential; Corrosion prevention; Corrosion resistance; Corrosion tests; Electrocatalysts; Evolution; Humanities and Social Sciences; multidisciplinary; Oxygen; Oxygen evolution reactions; Science; Science (multidisciplinary); Stability; Strain analysis; X ray absorption
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-024-53763-8

Enhancing corrosion resistance is essential for developing efficient electrocatalysts for acidic oxygen evolution reaction (OER). Herein, we report the strategic manipulation of the local compressive strain to reinforce the anti-corrosion properties of the non-precious Co 3 O 4 support. The incorporation of Ru single atoms, larger in atomic size than Co, into the Co 3 O 4 lattice (Ru-Co 3 O 4 ), triggers localized strain compression and lattice distortion on the Co-O lattice. A comprehensive exploration of the correlation between this specific local compressive strain and electrocatalytic performance is conducted through experimental and theoretical analyses. The presence of the localized strain in Ru-Co 3 O 4 is confirmed by operando X-ray absorption studies and supported by quantum calculations. This local strain, presented in a shortened Co-O bond length, enhances the anti-corrosion properties of Co 3 O 4 by suppressing metal dissolutions. Consequently, Ru-Co 3 O 4 shows satisfactory stability, maintaining OER for over 400 hours at 30 mA cm −2 with minimal decay. This study demonstrates the potential of the local strain effect in fortifying catalyst stability for acidic OER and beyond. Enhancing corrosion resistance is crucial for efficient electrocatalysts in the acidic oxygen evolution reaction. Here, the authors report the strategic manipulation of local compressive strain to improve the anti-corrosion properties of Co3O4, demonstrating stability for over 400 hours at 30 mA cm -2 .