Recent advances in the tandem annulation of 1,3-enynes to functionalized pyridine and pyrrole derivatives

Great progress has been made in the tandem annulation of enynes in the past few years. This review only presents the corresponding reactions of 1,3-enyne structural motifs to provide the functionalized pyridine and pyrrole derivatives. The functionalization reactions cover iodination, bromination, t...

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Published inBeilstein journal of organic chemistry Vol. 17; no. 1; pp. 2462 - 2476
Main Authors Liu, Yi, Luo, Puying, Fu, Yang, Hao, Tianxin, Liu, Xuan, Ding, Qiuping, Peng, Yiyuan
Format Journal Article
LanguageEnglish
Published Frankfurt am Main Beilstein-Institut zur Föerderung der Chemischen Wissenschaften 22.09.2021
Beilstein-Institut
Subjects
1,3-enyne
Acids
Alkylation
Ammonia
Bromination
Chemistry
Esterification
Free radicals
functionalization
Hydroxylation
Iodination
Laboratories
pyridine
Pyridines
pyrrole
Reaction mechanisms
Review
tandem annulation
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Abstract Great progress has been made in the tandem annulation of enynes in the past few years. This review only presents the corresponding reactions of 1,3-enyne structural motifs to provide the functionalized pyridine and pyrrole derivatives. The functionalization reactions cover iodination, bromination, trifluoromethylation, azidation, carbonylation, arylation, alkylation, selenylation, sulfenylation, amidation, esterification, and hydroxylation. We also briefly introduce the applications of the products and the reaction mechanisms for the synthesis of corresponding N-heterocycles.
AbstractList Great progress has been made in the tandem annulation of enynes in the past few years. This review only presents the corresponding reactions of 1,3-enyne structural motifs to provide the functionalized pyridine and pyrrole derivatives. The functionalization reactions cover iodination, bromination, trifluoromethylation, azidation, carbonylation, arylation, alkylation, selenylation, sulfenylation, amidation, esterification, and hydroxylation. We also briefly introduce the applications of the products and the reaction mechanisms for the synthesis of corresponding N-heterocycles.
Great progress has been made in the tandem annulation of enynes in the past few years. This review only presents the corresponding reactions of 1,3-enyne structural motifs to provide the functionalized pyridine and pyrrole derivatives. The functionalization reactions cover iodination, bromination, trifluoromethylation, azidation, carbonylation, arylation, alkylation, selenylation, sulfenylation, amidation, esterification, and hydroxylation. We also briefly introduce the applications of the products and the reaction mechanisms for the synthesis of corresponding N-heterocycles.Great progress has been made in the tandem annulation of enynes in the past few years. This review only presents the corresponding reactions of 1,3-enyne structural motifs to provide the functionalized pyridine and pyrrole derivatives. The functionalization reactions cover iodination, bromination, trifluoromethylation, azidation, carbonylation, arylation, alkylation, selenylation, sulfenylation, amidation, esterification, and hydroxylation. We also briefly introduce the applications of the products and the reaction mechanisms for the synthesis of corresponding N-heterocycles.
Author Hao, Tianxin
Liu, Xuan
Luo, Puying
Ding, Qiuping
Liu, Yi
Fu, Yang
Peng, Yiyuan
AuthorAffiliation 2 Department of Gynaecology, Jiangxi Provincial People’s Hospital Affiliated to Nanchang University, 92 Aiguo Road, Nanchang, Jiangxi, 330006, China
1 Key Laboratory for Green Chemistry of Jiangxi Province, Key Laboratory of Functional Small Organic Molecules, Ministry of Education, Jiangxi Normal University, 99 Ziyang Road, Nanchang 330022, China
AuthorAffiliation_xml – name: 2 Department of Gynaecology, Jiangxi Provincial People’s Hospital Affiliated to Nanchang University, 92 Aiguo Road, Nanchang, Jiangxi, 330006, China
– name: 1 Key Laboratory for Green Chemistry of Jiangxi Province, Key Laboratory of Functional Small Organic Molecules, Ministry of Education, Jiangxi Normal University, 99 Ziyang Road, Nanchang 330022, China
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SubjectTerms 1,3-enyne
Acids
Alkylation
Ammonia
Bromination
Chemistry
Esterification
Free radicals
functionalization
Hydroxylation
Iodination
Laboratories
pyridine
Pyridines
pyrrole
Reaction mechanisms
Review
tandem annulation
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Title Recent advances in the tandem annulation of 1,3-enynes to functionalized pyridine and pyrrole derivatives
URI https://www.proquest.com/docview/2595280062
https://www.proquest.com/docview/2580941962
https://pubmed.ncbi.nlm.nih.gov/PMC8474070
https://doaj.org/article/1e07410fdf0549298a2abc5f9a635c03
Volume 17
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