Anisotropy in spinodal-like dynamics of unknown water at ice V–water interface

• Published in: Scientific reports Vol. 13; no. 1; p. 16227
• Main Authors: Niinomi, Hiromasa, Yamazaki, Tomoya, Nada, Hiroki, Hama, Tetsuya, Kouchi, Akira, Oshikiri, Tomoya, Nakagawa, Masaru, Kimura, Yuki
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 11.10.2023; Nature Publishing Group; Nature Portfolio
• Subjects: 639/301/119/2795; 639/301/923/1030; 639/301/923/614; 639/301/923/919; 639/766/119/1002; 639/766/119/544; 704/445/125; Anisotropy; Crystallization; Humanities and Social Sciences; Interfaces; Light microscopy; Microscopy; Morphology; multidisciplinary; Polymorphism; Science; Science (multidisciplinary); Temperature
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-023-43295-4

Experimentally demonstrating the existence of waters with local structures unlike that of common water is critical for understanding both the origin of the mysterious properties of water and liquid polymorphism in single component liquids. At the interfaces between water and ices I h , III, and VI grown/melted under pressure, we previously discovered low- and high-density unknown waters, that are immiscible with the surrounding water. Here, we show, by in-situ optical microscopy, that an unknown water appears at the ice V–water interface via spinodal-like dynamics. The dewetting dynamics of the unknown water indicate that its characteristic velocity is ~ 90 m/s. The time evolution of the characteristic length of the spinodal-like undulation suggests that the dynamics may be described by a common model for spinodal decomposition of an immiscible liquid mixture. Spinodal-like dewetting dynamics of the unknown water transiently showed anisotropy, implying the property of a liquid crystal.