Controllable Patterning of Metallic Photonic Crystals for Waveguide-Plasmon Interaction

• Published in: Nanomaterials (Basel, Switzerland) Vol. 13; no. 4; p. 629
• Main Authors: Lin, Yuanhai, Che, Deqing, Hao, Wenjie, Dong, Yifei, Guo, Heng, Wang, Junsheng, Zhang, Xinping
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 05.02.2023; MDPI
• Subjects: Analysis; Aqueous solutions; Biosensors; Controllability; Crystals; Electron beam lithography; Extinction; Fabrication; Fano coupling; Glass substrates; Gold; High temperature; Identification and classification; Indium; Indium tin oxides; Light; Mechanical properties; metallic photonic crystals; Nanoparticles; Nanowires; Optical properties; Optics; Oxides; Pattern formation; patterning; Periodicity; Photonic crystals; Photonics; Photoresists; Polaritons; Polarization; Polymers; Self-assembly; Silver; Silver compounds; Slabs; Spectrum analysis; Tin compounds; Waveguides; waveguide–plasmon polaritons; China; Beijing China; United States > US; metallic photonic crystals; waveguide–plasmon polaritons; Fano coupling; patterning
• ISSN: 2079-4991; 2079-4991
• DOI: 10.3390/nano13040629

Waveguide-plasmon polaritons sustained in metallic photonic crystal slabs show fascinating properties, such as narrow bandwidth and ultrafast dynamics crucial for biosensing, light emitting, and ultrafast switching. However, the patterning of metallic photonic crystals using electron beam lithography is challenging in terms of high efficiency, large area coverage, and cost control. This paper describes a controllable patterning technique for the fabrication of an Ag grating structure on an indium-tin oxide (ITO) slab that enables strong photon-plasmon interaction to obtain waveguide-plasmon polaritons. The Ag grating consisting of self-assembled silver nanoparticles (NPs) exhibits polarization-independent properties for the excitation of the hybrid waveguide-plasmon mode. The Ag NP grating can also be annealed at high temperature to form a continuous nanoline grating that supports the hybrid waveguide-plasmon mode only under transverse magnetic (TM) polarization. We tuned the morphology and the periodicity of the Ag grating through the concentration of silver salt and the photoresist template, respectively, to manipulate the strong coupling between the plasmon and the waveguide modes of different orders.