Metal-Organic Frameworks: A Rapidly Growing Class of Versatile Nanoporous Materials

• Published in: Advanced materials (Weinheim) Vol. 23; no. 2; pp. 249 - 267
• Main Authors: Meek, Scott T., Greathouse, Jeffery A., Allendorf, Mark D.
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 11.01.2011; WILEY‐VCH Verlag
• Subjects: Catalysis; Cations; Chemical Fractionation; Computer Simulation; Detection; Drug Carriers - chemical synthesis; Drug Carriers - chemistry; Drug Delivery; Drug delivery systems; Electronics; Focusing; Metal-organic frameworks; Metals - chemistry; Nanomaterials; Nanopores; Nanostructure; Networks; Organic Chemicals - chemistry; Sensing; Separation
• ISSN: 0935-9648; 1521-4095; 1521-4095
• DOI: 10.1002/adma.201002854

Metal‐organic frameworks (MOFs) represent a new class of hybrid organic‐inorganic supramolecular materials comprised of ordered networks formed from organic electron donor linkers and metal cations. They can exhibit extremely high surface areas, as well as tunable pore size and functionality, and can act as hosts for a variety of guest molecules. Since their discovery, MOFs have enjoyed extensive exploration, with applications ranging from gas storage to drug delivery to sensing. This review covers advances in the MOF field from the past three years, focusing on applications, including gas separation, catalysis, drug delivery, optical and electronic applications, and sensing. We also summarize recent work on methods for MOF synthesis and computational modeling. Metal–organic frameworks (MOFs), such as MOF‐5 (see figure), represent a relatively new class of hybrid organic‐inorganic materials. This Progress Report summarizes recent advances in the field of MOFs with a focus on applications, including synthesis, computational modeling, gas separations, catalysis, drug delivery, optical and electronic properties, and sensing.