Tailoring Microporosity in Covalent Organic Frameworks

The microporosity of covalent organic frameworks (COFs) is tailored using a facile synthetic approach that introduces alkyl functionalities into the pore and generates networks with pore diameters between 1–2 nm. The added substituents significantly alter the host‐guest properties of the resulting m...

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Published inAdvanced materials (Weinheim) Vol. 20; no. 14; pp. 2741 - 2746
Main Authors Tilford, R. William, Mugavero III, Sam J., Pellechia, Perry J., Lavigne, John J.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 17.07.2008
WILEY‐VCH Verlag
Subjects
boronate esters
Covalence
covalent organic frameworks
Microporosity
Networks
polymeric materials
Porosity
porous materials
covalent organic frameworks
porous materials
boronate esters
polymeric materials
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Summary:The microporosity of covalent organic frameworks (COFs) is tailored using a facile synthetic approach that introduces alkyl functionalities into the pore and generates networks with pore diameters between 1–2 nm. The added substituents significantly alter the host‐guest properties of the resulting materials.
Bibliography:Financial support for this work was provided by the National Science Foundation (CHE-0415553, CHE-0718877). We also acknowledge Profs. Thomas Vogt and Hans Conrad zur Loye for helpful discussions. Supporting Information is available online from Wiley InterScience or from the author.
istex:02FE2F657E81F03D202CCB59D82E459B07F09644
National Science Foundation - No. CHE-0415553; No. CHE-0718877
ark:/67375/WNG-B245TSRC-2
ArticleID:ADMA200800030
Financial support for this work was provided by the National Science Foundation (CHE‐0415553, CHE‐0718877). We also acknowledge Profs. Thomas Vogt and Hans Conrad zur Loye for helpful discussions. Supporting Information is available online from Wiley InterScience or from the author.
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ISSN:0935-9648
1521-4095
DOI:10.1002/adma.200800030