Polymer Electrolytes for Lithium-Ion Batteries

• Published in: Advanced materials (Weinheim) Vol. 10; no. 6; pp. 439 - 448
• Main Author: Meyer, Wolfgang H.
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag GmbH 01.04.1998; WILEY‐VCH Verlag GmbH
• ISSN: 0935-9648; 1521-4095
• DOI: 10.1002/(SICI)1521-4095(199804)10:6<439::AID-ADMA439>3.0.CO;2-I

The motivation for lithium battery development and a discussion of ion conducting polymers as separators begin this review, which includes a short history of polymer electrolyte research, a summary of the major parameters that determine lithium ion transport in polymer matrices, and consequences for solid polymer electrolyte development. Two major strategies for the application of ion conducting polymers as separators in lithium batteries are identified: One is the development of highly conductive materials via the crosslinking of mobile chains to form networks, which are then swollen by lithium salt solutions (“gel electrolytes”). The other is the construction of solid polymer electrolytes (SPEs) with supramolecular architectures, which intrinsically give rise to much enhanced mechanical strength. These materials as yet exhibit relatively common conductivity levels but may be applied as very thin films. Molecular composites based on poly(p‐phenylene)‐ (PPP)‐reinforced SPEs are a striking example of this direction. Neither strategy has as yet led to a “breakthrough” with respect to technical application, at least not for electrically powered vehicles. Before being used as separators, the gel electrolytes must be strengthened, while the molecularly reinforced solid polymer electrolytes must demonstrate improved conductivity. Polymer electrolytes for lithium ion batteries is the theme of this review. Two major strategies for the application of ion‐conducting polymers as separators in lithium batteries are identified: the use of gel electrolytes and solid polymer electrolytes. The Figure illustrates the mechanism of cation transport in a lithium salt/poly(ethylene oxide) solid polymer electrolyte.