On the Effect of Birefringence on Light Transmission in Polycrystalline Magnesium Fluoride

• Published in: Journal of the American Ceramic Society Vol. 98; no. 3; pp. 829 - 837
• Main Authors: Wen, Tzu-Chien, Shetty, Dinesh K.
• Format: Journal Article
• Language: English
• Published: Columbus Blackwell Publishing Ltd 01.03.2015; Wiley Subscription Services, Inc
• Subjects: Annealing; Billets; Ceramics; Diffraction; Grain size; Light transmission; Magnesium fluorides; Mathematical models; Microstructure; Polycrystals; Scattering; Scattering coefficients; Wavelengths
• ISSN: 0002-7820; 1551-2916
• DOI: 10.1111/jace.13351

Light transmission in polycrystalline magnesium fluoride was studied as a function of the mean grain size at different wavelengths. The mean grain size was varied by annealing hot‐pressed billets in argon atmosphere at temperatures ranging from 600°C to 800°C for 1 h. The grain‐size and grain‐orientation distributions were characterized by electron back scatter diffraction. The scattering coefficients were calculated from the in‐line transmittance measured at various wavelengths. The scattering coefficient of polycrystalline magnesium fluoride increased linearly with the mean grain size and inversely with the square of the wavelength of light. It is shown that these trends are consistent with theoretical models based on both a limiting form of the Raleigh–Gans–Debye (RGD) theory of particle scattering and light retardation theories that take refractive index variations along the light path. Quantitative predictions of the theories are, however, subject to uncertainly due to the restrictive assumptions made in the theories and difficulties in representing the microstructure in the theoretical models. In particular, grain‐size distribution has a significant influence on the scattering coefficient calculated using particle scattering models.