Cross-linked polyelectrolyte for direct methanol fuel cells applications based on a novel sulfonated cross-linker

A novel type of cross-linked proton exchange membrane of lower methanol permeation and high proton conductivity is prepared, based on a newly synthesized sulfonated cross-linker: carboxyl terminated benzimidazole trimer bearing sulfonic acid groups (s-BI). Compared to membranes cross-linked with non...

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Published inJournal of power sources Vol. 255; pp. 101 - 107
Main Authors Li, Mingyu, Zhang, Gang, Xu, Shuai, Zhao, Chengji, Han, Miaomiao, Zhang, Liyuan, Jiang, Hao, Liu, Zhongguo, Na, Hui
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 01.06.2014
Elsevier
Subjects
Applied sciences
Crosslinking
Direct energy conversion and energy accumulation
Direct methanol fuel cells
Electrical engineering. Electrical power engineering
Electrical power engineering
Electrochemical conversion: primary and secondary batteries, fuel cells
Energy
Energy. Thermal use of fuels
Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc
Exact sciences and technology
Fuel cells
Mechanical properties
Membranes
Methyl alcohol
Polyelectrolytes
Proton exchange membrane
Sulfonated cross-linker
Sulfonated poly(ether ether ketone)
Sulfonic acid
Trimers
Sulfonated cross-linker
Direct methanol fuel cells
Proton exchange membrane
Sulfonated poly(ether ether ketone)
Polyetheretherketone
Alcohol fuel cells
Ether copolymer
Crosslinking
Crosslink agent
Primary alcohol
Ketone copolymer
Sulfonate copolymer
Crosslinked copolymer
Polyelectrolyte
Sulfonate polymer
Cation exchange membrane
Application
Proton exchange
Methanol
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Abstract A novel type of cross-linked proton exchange membrane of lower methanol permeation and high proton conductivity is prepared, based on a newly synthesized sulfonated cross-linker: carboxyl terminated benzimidazole trimer bearing sulfonic acid groups (s-BI). Compared to membranes cross-linked with non-sulfonated cross-linker (BI), SPEEK/s-BI-n membranes show higher IEC values and proton conductivities. Meanwhile, oxidative stability and mechanical property of SPEEK/s-BI-n membranes are obviously improved. Among SPEEK/s-BI-n membranes, SPEEK/s-BI-2 exhibits high proton conductivity, low swelling ratio (0.122 S cm−1 and 15.2% at 60 °C, respectively) and low methanol permeability coefficient. These results imply that the cross-linked membranes prepared with the newly sulfonated cross-linker are promising for the direct methanol fuel cells (DMFCs) application. •Cross-linker with proton conductive group was designed and synthesized.•A comparison between the sulfonated and non-sulfonated cross-linkers was made.•By using the sulfonated cross-linker, SPEEK has been successfully modified.•The result membranes showed low methanol crossover as well as high conductivity.•The oxidative stability of the result membranes was much improved also.
AbstractList A novel type of cross-linked proton exchange membrane of lower methanol permeation and high proton conductivity is prepared, based on a newly synthesized sulfonated cross-linker: carboxyl terminated benzimidazole trimer bearing sulfonic acid groups (s-BI). Compared to membranes cross-linked with non-sulfonated cross-linker (BI), SPEEK/s-BI-n membranes show higher IEC values and proton conductivities. Meanwhile, oxidative stability and mechanical property of SPEEK/s-BI-n membranes are obviously improved. Among SPEEK/s-BI-n membranes, SPEEK/s-BI-2 exhibits high proton conductivity, low swelling ratio (0.122 S cm−1 and 15.2% at 60 °C, respectively) and low methanol permeability coefficient. These results imply that the cross-linked membranes prepared with the newly sulfonated cross-linker are promising for the direct methanol fuel cells (DMFCs) application. •Cross-linker with proton conductive group was designed and synthesized.•A comparison between the sulfonated and non-sulfonated cross-linkers was made.•By using the sulfonated cross-linker, SPEEK has been successfully modified.•The result membranes showed low methanol crossover as well as high conductivity.•The oxidative stability of the result membranes was much improved also.
A novel type of cross-linked proton exchange membrane of lower methanol permeation and high proton conductivity is prepared, based on a newly synthesized sulfonated cross-linker: carboxyl terminated benzimidazole trimer bearing sulfonic acid groups (s-BI). Compared to membranes cross-linked with non-sulfonated cross-linker (BI), SPEEK/s-BI-n membranes show higher IEC values and proton conductivities. Meanwhile, oxidative stability and mechanical property of SPEEK/s-BI-n membranes are obviously improved. Among SPEEK/s-BI-n membranes, SPEEK/s-BI-2 exhibits high proton conductivity, low swelling ratio (0.122 S cm super(-1) and 15.2% at 60 [degrees]C, respectively) and low methanol permeability coefficient. These results imply that the cross-linked membranes prepared with the newly sulfonated cross-linker are promising for the direct methanol fuel cells (DMFCs) application.
Author Zhang, Liyuan
Na, Hui
Liu, Zhongguo
Zhang, Gang
Han, Miaomiao
Li, Mingyu
Xu, Shuai
Zhao, Chengji
Jiang, Hao
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Keywords Sulfonated cross-linker
Direct methanol fuel cells
Proton exchange membrane
Sulfonated poly(ether ether ketone)
Polyetheretherketone
Alcohol fuel cells
Ether copolymer
Crosslinking
Crosslink agent
Primary alcohol
Ketone copolymer
Sulfonate copolymer
Crosslinked copolymer
Polyelectrolyte
Sulfonate polymer
Cation exchange membrane
Application
Proton exchange
Methanol
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Snippet A novel type of cross-linked proton exchange membrane of lower methanol permeation and high proton conductivity is prepared, based on a newly synthesized...
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SubjectTerms Applied sciences
Crosslinking
Direct energy conversion and energy accumulation
Direct methanol fuel cells
Electrical engineering. Electrical power engineering
Electrical power engineering
Electrochemical conversion: primary and secondary batteries, fuel cells
Energy
Energy. Thermal use of fuels
Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc
Exact sciences and technology
Fuel cells
Mechanical properties
Membranes
Methyl alcohol
Polyelectrolytes
Proton exchange membrane
Sulfonated cross-linker
Sulfonated poly(ether ether ketone)
Sulfonic acid
Trimers
Title Cross-linked polyelectrolyte for direct methanol fuel cells applications based on a novel sulfonated cross-linker
URI https://dx.doi.org/10.1016/j.jpowsour.2013.12.116
https://www.proquest.com/docview/1544017974
https://www.proquest.com/docview/1677909696
Volume 255
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