Effects of Alternate Wet and Dry Conditions on the Mechanical and Physical Performance of Limestone Calcined Clay Cement Mortars Immersed in Sodium Sulfate Media

• Published in: Materials Vol. 15; no. 24; p. 8935
• Main Authors: Odhiambo, Vincent Odhiambo, Scheinherrová, Lenka, Abuodha, Silvester Ochieng, Mwero, John Nyiro, Marangu, Joseph Mwiti
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 14.12.2022; MDPI
• Subjects: Analysis; calcined clay; Carbon dioxide; Cement hydration; Clay; Climate change; Clinker; Composition; Compressive strength; Concrete; Concrete structures; Curing; Drying; durability; Emissions; Global temperature changes; Gypsum; Limestone; Mixtures; Mortars (material); ordinary Portland cement; Performance evaluation; Portland cements; Roasting; Sewer systems; Sodium; Sodium sulfate; Soils; sorptivity; Sulfates; supplementary cementitious materials; Wetting; Kenya; compressive strength; supplementary cementitious materials; calcined clay; ordinary Portland cement; sorptivity; durability
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma15248935

Sulfate attack in concrete structures significantly reduces their durability. This article reports the experimental findings on the effects of sodium sulfate on limestone calcined clay cement (LC ) in an alternate wet and dry media. The samples underwent wet-dry conditions of 28 cycles. Two types of LC were studied, one made from clay (LC -CL) and the other made from fired rejected clay bricks (LC -FR). The composition of each LC blend by weight was 50% clinker, 30% calcined clay, 15% limestone, and 5% gypsum. The reference compressive strength was evaluated at 2, 7, and 28 days of age. Then, ordinary Portland cement (OPC) and LC -CL blends were subjected to alternate wet-dry cycle tests, immersion in a 5% sodium sulfate solution, or in water. For all exposed samples, sorptivity tests and compressive strength were done. The results showed that LC blends met the requirements for KS-EAS 18-1:2017 standard, which specifies the composition and conformity criteria for common cements in Kenya. The LC blend also had a lower rate of initial absorption compared to OPC. Additionally, LC blend also showed good resistance to sodium sulfate when exposed to alternating wetting and drying environment. OPC showed higher compressive strength than LC blends for testing ages of 2, 7, and 28 days. However, the LC samples utilized in the sodium sulfate attack experiment, which were later tested after 84 days, exhibited higher compressive strengths than OPC tested after the same period.