Breaking Azacalix[4]arenes into Induline Derivatives

Tetraamino-tetranitro-azacalixarene is at the crossroad of two different families of compounds depending on the conditions and the agent used to reduce the NO groups: (1) azacalixphyrin in neutral medium, or (2) phenazinium of type in acidic medium. The key role of the N-substituted amino functions...

Full description

Saved in:
Bibliographic Details
Published inMolecules (Basel, Switzerland) Vol. 28; no. 24; p. 8113
Main Authors Chen, Zhongrui, Canard, Gabriel, Grauby, Olivier, Mourot, Benjamin, Siri, Olivier
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 15.12.2023
MDPI
Subjects
azacalixarenes
Chemical Sciences
Hydrogenation
macrocycles
nanostructure
Nitrogen
Oxidation
phenazinium
nanostructure
azacalixarenes
macrocycles
phenazinium
Online AccessGet full text

Cover

More Information
Summary:Tetraamino-tetranitro-azacalixarene is at the crossroad of two different families of compounds depending on the conditions and the agent used to reduce the NO groups: (1) azacalixphyrin in neutral medium, or (2) phenazinium of type in acidic medium. The key role of the N-substituted amino functions at the periphery is highlighted by investigating octaaminoazacalixarene as a model compound, and by using the corresponding tetrahydroxy-tetranitro-azacalixarene as a precursor, which behaves differently.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules28248113