Novel Approach for Enhanced Scandium and Titanium Leaching Efficiency from Bauxite Residue with Suppressed Silica Gel Formation

• Published in: Scientific reports Vol. 8; no. 1; pp. 5676 - 11
• Main Authors: Alkan, Gözde, Yagmurlu, Bengi, Cakmakoglu, Seckin, Hertel, Tobias, Kaya, Şerif, Gronen, Lars, Stopic, Srecko, Friedrich, Bernd
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 04.04.2018; Nature Publishing Group
• Subjects: 639/166; 639/166/898; 639/301; Alloys; Efficiency; Environmental aspects; Humanities and Social Sciences; Hydrogen peroxide; Leaching; Metals; Mineralogy; multidisciplinary; Precipitation; Scandium; Science; Science (multidisciplinary); Silica; Silica gel; Sulfuric acid; Titanium; Transportation industry
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-018-24077-9

The need of light weight alloys for future transportation industry puts Sc and Ti under a sudden demand. While these metals can bring unique and desired properties to alloys, lack of reliable sources brought forth a supply problem which can be solved by valorization of the secondary resources. Bauxite residue (red mud), with considerable Ti and Sc content, is a promising resource for secure supply of these metals. Due to drawbacks of the direct leaching route from bauxite residue, such as silica gel formation and low selectivity towards these valuable metals, a novel leaching process based on oxidative leaching conditions, aiming more efficient and selective leaching but also considering environmental aspects via lower acid consumption, was investigated in this study. Combination of hydrogen peroxide (H 2 O 2 ) and sulfuric acid (H 2 SO 4 ) was utilized as the leaching solution, where various acid concentrations, solid-to-liquid ratios, leaching temperatures and times were examined in a comparative manner. Leaching with 2.5 M H 2 O 2 : 2.5 M H 2 SO 4 mixture at 90 °C for 30 min was observed to be the best leaching conditions with suppressed silica gel formation and the highest reported leaching efficiency with high S/L ratio for Sc and Ti; 68% and 91%; respectively.