Ceramic strengthening by tuning the elastic moduli of resin-based luting agents

• Published in: Dental materials Vol. 33; no. 3; pp. 358 - 366
• Main Authors: Spazzin, Aloísio O, Bacchi, Ataís, Alessandretti, Rodrigo, Santos, Mateus B, Basso, Gabriela R, Griggs, Jason, Moraes, Rafael R
• Format: Journal Article
• Language: English
• Published: England Elsevier Ltd 01.03.2017; Elsevier BV
• Subjects: 3D finite element analysis; Acid-sensitive ceramics; Acids; Advanced Basic Science; Ceramic coatings; Ceramics; Dental cement; Dental Cements; Dental Porcelain; Dentistry; Disks; Electron microscopy; Etching; Failure; Finite element analysis; Finite element method; Flexural strength; Fractography; Interfaces; Irregularities; Materials Testing; Mechanical strength; Modulus of elasticity; Modulus of rupture in bending; Morphology; Reliability engineering; Reproducibility of Results; Resin Cements; Scanning electron microscopy; Stress concentration; Stress, Mechanical; Structural reliability; Surface Properties; Weibull analysis; Weibull modulus; Acid-sensitive ceramics; Mechanical strength; 3D finite element analysis; Fractography; Weibull analysis
• ISSN: 0109-5641; 1879-0097
• DOI: 10.1016/j.dental.2017.01.002

Abstract Objective Resin-based luting agents (RBLAs) with tuned elastic moduli ( E ) were prepared and their influence on the strengthening, reliability, and mode of failure of luted feldspar ceramic was investigated. Methods RBLAs with low E (2.6 GPa), intermediate E (6.6 GPa), and high E (13.3 GPa) were prepared and used to coat acid-etched ceramic disks. Positive (untreated ceramic) and negative (acid-etched ceramic) control groups were tested. The response variables (n = 30) were biaxial flexural strength ( σbf , MPa), characteristic strength ( σ0 , MPa), and Weibull modulus at the ceramic surface (z = 0) and luting agent surface (z = −t2 ). A 3D finite element analysis simulated the biaxial flexural test. Fractographic analysis and morphology of the bonded interfaces were analyzed using scanning electron microscopy. Results The RBLAs improved σbf and σ0 at z = 0, particularly those with intermediate and high E , whereas the mechanical reliability was only affected in the negative control. At z = −t2 , differences between all RBLAs were observed but the structural reliability was independent of the RBLA tested. Increasing E of the RBLA was associated with increased stress concentration at the RBLA and reduced stresses reaching the ceramic. Failures originated on the ceramic surface at the ceramic-cement interface. In the high E group, failure sometimes originated from the RBLA free surface. All RBLAs completely filled the ceramic irregularities. Significance Increased E of the RBLA reduced the variability of strength, the stress reaching the ceramic structure, and sometimes altered the origin of failure. The use of high E RBLAs seems beneficial for luting feldspar ceramics.