Traveling-waves of metal-containing monomer polymerization without diffusion and heat-transfer

The new approach for modeling kinetics of complex spatial self-propagating traveling-wave reactions is proposed. This approach is intended to replace well-known reaction–diffusion equations and self-propagating high-temperature synthesis (SHS) as methods for mathematical modeling of spatial propagat...

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Bibliographic Details
Published inHeliyon Vol. 5; no. 11; p. e02829
Main Authors Zakiev, S.E., Shershnev, V.A., Yadav, B.C., Kvurt, Yu.P., Dzhardimalieva, G.I.
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.11.2019
Elsevier
Subjects
Chemical kinetics
Condensed matter physics
Frontal polymerization
Materials science
Mathematical modelling
Metal-containing monomers
Thermodynamics
Travelling-waves
Thermodynamics
Metal-containing monomers
Condensed matter physics
Frontal polymerization
Chemical kinetics
Materials science
Mathematical modelling
Travelling-waves
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Summary:The new approach for modeling kinetics of complex spatial self-propagating traveling-wave reactions is proposed. This approach is intended to replace well-known reaction–diffusion equations and self-propagating high-temperature synthesis (SHS) as methods for mathematical modeling of spatial propagation of chemical reactions. A chemical kinetic model for frontal polymerization of metal-containing monomers under this approach is suggested. Condensed matter physics; Thermodynamics; Materials Science, Mathematical Modelling; Chemical Kinetics; frontal polymerization; metal-containing monomers; travelling-waves.
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ISSN:2405-8440
2405-8440
DOI:10.1016/j.heliyon.2019.e02829