A Chiral, Self-Catenating and Porous Metal-Organic Framework and its Post-Synthetic Metal Uptake

Free vacancies: A robust and porous metal–organic framework material with unique 4‐connected self‐catenating structure of {85⋅10} topology was synthesized. The structure features empty bipyridine metal‐chelating sites that can be doped with copper cations in a single‐crystal‐to‐single‐crystal post‐s...

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Published inAngewandte Chemie International Edition Vol. 51; no. 21; pp. 5192 - 5195
Main Authors Jacobs, Tia, Clowes, Rob, Cooper, Andrew I., Hardie, Michaele J.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 21.05.2012
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
Cations
Copper
metal doping
Metal-organic frameworks
Metals
network topologies
nitrogen sorption
Pictures
post-synthetic modification
Single crystals
Topology
Uptakes
Vacancies
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Summary:Free vacancies: A robust and porous metal–organic framework material with unique 4‐connected self‐catenating structure of {85⋅10} topology was synthesized. The structure features empty bipyridine metal‐chelating sites that can be doped with copper cations in a single‐crystal‐to‐single‐crystal post‐synthetic modification (see picture; scale bar 20 μm).
Bibliography:istex:B608212CEBAB3D25BC30E1D0221427B0516378BB
The Leverhulme Trust (UK)
The authors thank the Diamond Light Source and S. Barnett for access to and assistance with diffraction facilities; M. A. Halcrow and J. Loughrey for assistance with ESR and A. Kulak with optical microscopy; A. Kazlauciunas for SEM-EDX measurements; I. Blakeley for microanalysis; and F. Meldrum and B. Murray for access to equipment. This work was funded by The Leverhulme Trust (UK).
ark:/67375/WNG-ZF0W9C6W-S
ArticleID:ANIE201200758
The authors thank the Diamond Light Source and S. Barnett for access to and assistance with diffraction facilities; M. A. Halcrow and J. Loughrey for assistance with ESR and A. Kulak with optical microscopy; A. Kazlauciunas for SEM‐EDX measurements; I. Blakeley for microanalysis; and F. Meldrum and B. Murray for access to equipment. This work was funded by The Leverhulme Trust (UK).
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ISSN:1433-7851
1521-3773
1521-3773
DOI:10.1002/anie.201200758