Merging Visible‐Light Catalysis for the Direct Late‐Stage Group‐16–Trifluoromethyl Bond Formation
The use of visible light activation/photoredox chemistry for the generation of radical‐centered chalcogen–CF3 has gained widespread interest in the last past three years. Its subsequent reactivity for the synthesis of new chalcogen–CF3‐containing building blocks gained much attention. To date severa...
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| Published in | Chemistry : a European journal Vol. 25; no. 26; pp. 6482 - 6495 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
Wiley Subscription Services, Inc
07.05.2019
Wiley-VCH Verlag |
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| Abstract | The use of visible light activation/photoredox chemistry for the generation of radical‐centered chalcogen–CF3 has gained widespread interest in the last past three years. Its subsequent reactivity for the synthesis of new chalcogen–CF3‐containing building blocks gained much attention. To date several methodologies have been developed addressing several challenges in modern organofluorine chemistry and enabled substantial progress in substrates scope and reaction conditions. This review describes these advancements with a particular focus on the reaction mechanisms.
The use of visible‐light/photoredox catalysis emerged recently as a powerful tool for the generation of chalcogen trifluoromethyl‐centred radicals and their subsequent incorporation in organic building blocks. The developed methodologies are highlighted herein. |
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| AbstractList | The use of visible light activation/photoredox chemistry for the generation of radical-centered chalcogen-CF3 has gained widespread interest in the last past three years. Its subsequent reactivity for the synthesis of new chalcogen-CF3 -containing building blocks gained much attention. To date several methodologies have been developed addressing several challenges in modern organofluorine chemistry and enabled substantial progress in substrates scope and reaction conditions. This review describes these advancements with a particular focus on the reaction mechanisms. Abstract The use of visible light activation/photoredox chemistry for the generation of radical‐centered chalcogen–CF 3 has gained widespread interest in the last past three years. Its subsequent reactivity for the synthesis of new chalcogen–CF 3 ‐containing building blocks gained much attention. To date several methodologies have been developed addressing several challenges in modern organofluorine chemistry and enabled substantial progress in substrates scope and reaction conditions. This review describes these advancements with a particular focus on the reaction mechanisms. The use of visible light activation/photoredox chemistry for the generation of radical-centered chalcogen-CF has gained widespread interest in the last past three years. Its subsequent reactivity for the synthesis of new chalcogen-CF -containing building blocks gained much attention. To date several methodologies have been developed addressing several challenges in modern organofluorine chemistry and enabled substantial progress in substrates scope and reaction conditions. This review describes these advancements with a particular focus on the reaction mechanisms. The use of visible light activation/photoredox chemistry for the generation of radical‐centered chalcogen–CF3 has gained widespread interest in the last past three years. Its subsequent reactivity for the synthesis of new chalcogen–CF3‐containing building blocks gained much attention. To date several methodologies have been developed addressing several challenges in modern organofluorine chemistry and enabled substantial progress in substrates scope and reaction conditions. This review describes these advancements with a particular focus on the reaction mechanisms. The use of visible‐light/photoredox catalysis emerged recently as a powerful tool for the generation of chalcogen trifluoromethyl‐centred radicals and their subsequent incorporation in organic building blocks. The developed methodologies are highlighted herein. |
| Author | Ghiazza, Clément Billard, Thierry Tlili, Anis |
| Author_xml | – sequence: 1 givenname: Clément surname: Ghiazza fullname: Ghiazza, Clément organization: Univ Lyon, Université Lyon 1, CNRS – sequence: 2 givenname: Thierry surname: Billard fullname: Billard, Thierry organization: Groupement Hospitalier Est – sequence: 3 givenname: Anis orcidid: 0000-0002-3058-2043 surname: Tlili fullname: Tlili, Anis email: anis.tlili@univ-lyon1.fr organization: Univ Lyon, Université Lyon 1, CNRS |
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| Keywords | catalysis trifluoromethyl photoredox chalcogens fluorine |
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| Snippet | The use of visible light activation/photoredox chemistry for the generation of radical‐centered chalcogen–CF3 has gained widespread interest in the last past... The use of visible light activation/photoredox chemistry for the generation of radical-centered chalcogen-CF has gained widespread interest in the last past... Abstract The use of visible light activation/photoredox chemistry for the generation of radical‐centered chalcogen–CF 3 has gained widespread interest in the... The use of visible light activation/photoredox chemistry for the generation of radical-centered chalcogen-CF3 has gained widespread interest in the last past... |
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| SubjectTerms | Catalysis chalcogens Chemical Sciences Chemistry fluorine Organic chemistry photoredox Reaction mechanisms Substrates trifluoromethyl |
| Title | Merging Visible‐Light Catalysis for the Direct Late‐Stage Group‐16–Trifluoromethyl Bond Formation |
| URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchem.201806234 https://www.ncbi.nlm.nih.gov/pubmed/30644601 https://www.proquest.com/docview/2220697561 https://search.proquest.com/docview/2179366541 https://udl.hal.science/hal-02107065 |
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