A cost effective and facile approach to prepare beadless polycarbonate nanofibers with ultrafine fiber morphology

• Published in: Polymer engineering and science Vol. 59; no. 9; pp. 1799 - 1809
• Main Authors: Baby, Thomas, Jose E, Tomlal, Thomas, P.C., Mathew, Jomit T.
• Format: Journal Article
• Language: English
• Published: Hoboken, USA John Wiley & Sons, Inc 01.09.2019; Society of Plastics Engineers, Inc; Blackwell Publishing Ltd
• Subjects: Composition; Dichloromethane; Dimethylformamide; Electrospinning; Fibers; Materials research; Morphology; Nanofibers; Nanotechnology; Parameters; Personal computers; Polycarbonate resins; Polycarbonates; Polymers; Production processes; Properties; Solvents; Technology; Ultrafines; India
• ISSN: 0032-3888; 1548-2634
• DOI: 10.1002/pen.25180

Preparing defect free nanofibers with average diameter well below 100 nm is a challenge to researchers by electrospinning technology. In the present contribution, the electrospinning method was utilized to prepare beadless polycarbonate (PC) nanofibers with average diameter 90 nm using comparatively less toxic and suitable solvents in a convenient way. Spinning PC with pure dichloromethane (DCM) and also with 1:1 mixture of DCM and N,N dimethylformamide under the same spinning parameters with varying PC concentration has very much helped to establish the effect of solvents on fiber formation. This study also proved the impact of solution concentration, viscosity, and solution conductivity on the formation of beadless ultrafine PC fibers and subsequently on the bead density and average fiber diameter. The appropriate proportion of solvents under suitable spinning parameters has helped to minimize the quantity of PC during the formation of bead free nanofibers by electrospinning. The ultrafine, uniform, and beadless morphology of the electrospun PC fibers can be utilized for various nanotechnology advancements. POLYM. ENG. SCI., 59:1799–1809, 2019. © 2019 Society of Plastics Engineers