Functionalization of heterocyclic compounds using polyfunctional magnesium and zinc reagents

In this review we summarize the most important procedures for the preparation of functionalized organzinc and organomagnesium reagents. In addition, new methods for the preparation of polyfunctional aryl- and heteroaryl zinc- and magnesium compounds, as well as new Pd-catalyzed cross-coupling reacti...

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Published inBeilstein journal of organic chemistry Vol. 7; no. 1; pp. 1261 - 1277
Main Authors Knochel, Paul, Schade, Matthias A, Bernhardt, Sebastian, Manolikakes, Georg, Metzger, Albrecht, Piller, Fabian M, Rohbogner, Christoph J, Mosrin, Marc
Format Journal Article
LanguageEnglish
Published Germany Beilstein-Institut 13.09.2011
Subjects
Chemistry
cross-coupling
heterocycles
insertion
metalation
organomagnesium
organozinc
Review
cross-coupling
insertion
organozinc
metalation
heterocycles
organomagnesium
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Summary:In this review we summarize the most important procedures for the preparation of functionalized organzinc and organomagnesium reagents. In addition, new methods for the preparation of polyfunctional aryl- and heteroaryl zinc- and magnesium compounds, as well as new Pd-catalyzed cross-coupling reactions, are reported herein. Experimental details are given for the most important reactions in the Supporting Information File 1 of this article.
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ISSN:1860-5397
1860-5397
DOI:10.3762/bjoc.7.147