Stereodivergent approach in the protected glycal synthesis of L-vancosamine, L-saccharosamine, L-daunosamine and L-ristosamine involving a ring-closing metathesis step
In this paper, a new access to several chiral 3-aminoglycals as potential precursors for glycosylated natural products is reported from a common starting material, (-)-methyl-L-lactate. The stereodivergent strategy is based on the implementation of a ring-closing metathesis of vinyl ethers as key st...
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Published in | Beilstein journal of organic chemistry Vol. 14; no. 1; pp. 2949 - 2955 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Germany
Beilstein-Institut zur Föerderung der Chemischen Wissenschaften
29.11.2018
Beilstein-Institut |
Subjects | |
Online Access | Get full text |
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Summary: | In this paper, a new access to several chiral 3-aminoglycals as potential precursors for glycosylated natural products is reported from a common starting material, (-)-methyl-L-lactate. The stereodivergent strategy is based on the implementation of a ring-closing metathesis of vinyl ethers as key step of reaction sequences developed. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 PMCID: PMC6278755 |
ISSN: | 1860-5397 2195-951X 1860-5397 |
DOI: | 10.3762/bjoc.14.274 |