Stacked Platinum Complexes of the Magnus' Salt Type Inside a Coordination Cage

Neatly wrapped up: Alternately stacked square‐planar platinum(II) complexes inside a dinuclear coordination cage were prepared to give a discrete and soluble Pt5‐array of the Magnus' salt type. Characterization of the complex in solution was complemented by an X‐ray crystal structure of {[Pt(py...

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Published inAngewandte Chemie (International ed.) Vol. 51; no. 11; pp. 2606 - 2609
Main Authors Clever, Guido H., Kawamura, Wataru, Tashiro, Shohei, Shiro, Motoo, Shionoya, Mitsuhiko
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 12.03.2012
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
Arrays
Cage
cage compounds
Circularity
Crystal structure
host-guest systems
metal stacking
Platinum
Superstructures
supramolecular chemistry
X-rays
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Summary:Neatly wrapped up: Alternately stacked square‐planar platinum(II) complexes inside a dinuclear coordination cage were prepared to give a discrete and soluble Pt5‐array of the Magnus' salt type. Characterization of the complex in solution was complemented by an X‐ray crystal structure of {[Pt(pyridine)4]⋅ [PtCl4]2@Cage}; this structure showed the linear, pentanuclear array within the cages and their circular packing into a hollow tubular superstructure.
Bibliography:MEXT of Japan
ark:/67375/WNG-ZTK4V16V-0
ArticleID:ANIE201108197
G.C. thanks the JSPS and the Alexander von Humboldt Foundation for a postdoctoral scholarship. This work was supported by Grants-in-Aid from MEXT of Japan and the Global COE Program for Chemistry Innovation.
istex:1580A14FF623F6FDB61131E576C3CFDE8E0C233E
G.C. thanks the JSPS and the Alexander von Humboldt Foundation for a postdoctoral scholarship. This work was supported by Grants‐in‐Aid from MEXT of Japan and the Global COE Program for Chemistry Innovation.
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201108197