Oceanic bromoform emissions weighted by their ozone depletion potential

• Published in: Atmospheric chemistry and physics Vol. 15; no. 23; pp. 13647 - 13663
• Main Authors: Tegtmeier, S, Ziska, F, Pisso, I, Quack, B, Velders, G. J. M, Yang, X, Krüger, K
• Format: Journal Article
• Language: English
• Published: Katlenburg-Lindau Copernicus GmbH 10.12.2015; Copernicus; Copernicus Publications
• Subjects: Air pollution; Analysis; Anthropogenic factors; Atmospheric ozone; Bromine; Chlorine; Chlorofluorocarbons; Climate; Climate change; Convective activity; Depletion; Distribution; Emissions; Environmental aspects; Equator; Estimates; Future climates; Halocarbons; Halogens; Human influences; Mass flux; Ozone; Ozone depletion; Ozone layer depletion; Spatial distribution; Stratosphere; Time series; Tropical climate; Tropical convective activity; Troposphere; Upper troposphere; Canada; Montreal Quebec Canada
• ISSN: 1680-7324; 1680-7316; 1680-7324
• DOI: 10.5194/acp-15-13647-2015

At present, anthropogenic halogens and oceanic emissions of very short-lived substances (VSLSs) both contribute to the observed stratospheric ozone depletion. Emissions of the long-lived anthropogenic halogens have been reduced and are currently declining, whereas emissions of the biogenic VSLSs are expected to increase in future climate due to anthropogenic activities affecting oceanic production and emissions. Here, we introduce a new approach for assessing the impact of oceanic halocarbons on stratospheric ozone by calculating their ozone depletion potential (ODP)-weighted emissions. Seasonally and spatially dependent, global distributions are derived within a case-study framework for CHBr3 for the period 1999–2006. At present, ODP-weighted emissions of CHBr3 amount up to 50 % of ODP-weighted anthropogenic emissions of CFC-11 and to 9 % of all long-lived ozone depleting halogens. The ODP-weighted emissions are large where strong oceanic emissions coincide with high-reaching convective activity and show pronounced peaks at the Equator and the coasts with largest contributions from the Maritime Continent and western Pacific Ocean. Variations of tropical convective activity lead to seasonal shifts in the spatial distribution of the trajectory-derived ODP with the updraught mass flux, used as a proxy for trajectory-derived ODP, explaining 71 % of the variance of the ODP distribution. Future climate projections based on the RCP 8.5 scenario suggest a 31 % increase of the ODP-weighted CHBr3 emissions by 2100 compared to present values. This increase is related to a larger convective updraught mass flux in the upper troposphere and increasing emissions in a future climate. However, at the same time, it is reduced by less effective bromine-related ozone depletion due to declining stratospheric chlorine concentrations. The comparison of the ODP-weighted emissions of short- and long-lived halocarbons provides a new concept for assessing the overall impact of oceanic halocarbon emissions on stratospheric ozone depletion for current conditions and future projections.