Binuclear C^C Cyclometalated Platinum(II) NHC Complexes with Bridging Amidinate Ligands
Binuclear C^C* cyclometalated NHC platinum(II) compounds with bridging amidinate ligands were synthesized to evaluate their photophysical properties. Their three‐dimensional structures were determined by a combination of 2D NMR experiments, mass spectrometry, DFT calculations, and solid‐state struct...
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Published in | Angewandte Chemie (International ed.) Vol. 55; no. 51; pp. 15779 - 15782 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Germany
Blackwell Publishing Ltd
19.12.2016
Wiley Subscription Services, Inc |
Edition | International ed. in English |
Subjects | |
Online Access | Get full text |
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Summary: | Binuclear C^C* cyclometalated NHC platinum(II) compounds with bridging amidinate ligands were synthesized to evaluate their photophysical properties. Their three‐dimensional structures were determined by a combination of 2D NMR experiments, mass spectrometry, DFT calculations, and solid‐state structure analysis. The bridging amidinate ligands enforce short distances between the platinum centers of the two cyclometalated structures, which gives rise to extraordinary photophysical properties.
Two phosphorescent binuclear C^C* cyclometalated PtII complexes bridged by N,N‐diphenylformamidinate ligands were synthesized and characterized by 2D NMR experiments, mass spectrometry, DFT calculations, and solid‐state structure analysis. The bridging amidinate ligands bring the two platinum centers into close proximity, which leads to extraordinary photophysical properties. |
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Bibliography: | ArticleID:ANIE201607075 istex:6FB8A548442B6C6AA9DD616744059832DACF11CE ark:/67375/WNG-W9VNJG1B-G ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.201607075 |