The '2+1' Construction of Homooxacalix[3]arenes Possessing Different Substituents on Their Upper Rims

Several homoxacalix[3]arenes possessing different substituents on their upper rims were synthesized in yields of 7-20% by a condensation reaction between the p-substituted phenol dimer and monomer under acidic high-dilution conditions.

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Bibliographic Details
Published inChemical & pharmaceutical bulletin Vol. 48; no. 6; pp. 882 - 884
Main Authors TSUBAKI, Kazunori, MUKOYOSHI, Koichiro, OTSUBO, Tadamune, FUJI, Kaoru
Format Journal Article
LanguageEnglish
Published TOKYO The Pharmaceutical Society of Japan 01.06.2000
Pharmaceutical Soc Japan
Maruzen
Japan Science and Technology Agency
Subjects
calixarene
Calixarenes
Chemistry
Chemistry, Medicinal
Chemistry, Multidisciplinary
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives
homooxacalixarene
host compound
Life Sciences & Biomedicine
Macromolecular Substances
molecular recognition
Molecular Structure
Organic chemistry
Pharmacology & Pharmacy
Physical Sciences
Preparations and properties
Science & Technology
Spectrum Analysis
RECOGNITION
homooxacalixarene
HEXAHOMOTRIOXACALIX ARENE
molecular recognition
host compound
calixarene
AMMONIUM-IONS
COMPLEXATION
DERIVATIVES
CONFORMERS
BINDING
SOLID-STATE
Condensation reaction
Perchloric acid
Calixarene
Tetracyclic compound
Cyclophane
Inclusion compound
Oxygen heterocycle
Chemical synthesis
Acidic solution
Macrocycle
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Summary:Several homoxacalix[3]arenes possessing different substituents on their upper rims were synthesized in yields of 7-20% by a condensation reaction between the p-substituted phenol dimer and monomer under acidic high-dilution conditions.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.48.882