Electrochromic and electrochemical capacitive properties of tungsten oxide and its polyaniline nanocomposite films obtained by chemical bath deposition method

• Published in: Electrochimica acta Vol. 128; pp. 218 - 225
• Main Authors: Nwanya, Assumpta C., Jafta, Charl J., Ejikeme, Paul M., Ugwuoke, Paulinus E., Reddy, M.V., Osuji, Rose U., Ozoemena, Kenneth I., Ezema, Fabian I.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 10.05.2014
• Subjects: Atomic force microscopy; Capacitance; Chemical bath deposition; Deposition; Electrochemical capacitors; Electrochemical impedance spectroscopy; Electrochromism; Nanostructure; PANI film; Scanning electron microscopy; Tungsten oxides; WO3/PANI film; PANI film; WO3/PANI film; Electrochromism; Chemical bath deposition; Electrochemical capacitors
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2013.10.002

Polyanine and its nanocomposite WO3/PANI films were deposited on fluorine doped tin oxide (FTO) glass slides by simple chemical bath deposition method. The morphology structure of the composite film was studied using atomic force microscopy (AFM) and scanning electron microscopy (SEM), while the electrochemical capacitive properties were determined using cyclic voltammetry (CV), chronopotentiometry (CP) and electrochemical impedance spectroscopy (EIS). The WO3/PANI nano-composite exhibited multiple colors (electrochromism) during the CV scans, from brownish green to transparent to light green then back to brownish green. Surprisingly, the integration of the PANI with the WO3 led to synergistic performance of nanohybrid wherein a true electrochemical double layer capacitor was obtained. Also, interestingly and unlike literature reports, the CBD method led to excellent capacitance retention (>98%) of the PANI even at 1000 continuous cycles. This work demonstrates that simple CBD can be used to get WO3/PANI films that give good electrochromism and pseudo-capacitance comparable to the ones obtained by other methods. Hence the obtained nanocomposite film of WO3/PANI can be a promising material for electrochromic and energy storage applications.