Analysis of extinction in ultraviolet and visible spectra of water bodies of the Paraguay and Brazil wetlands

• Published in: Chemosphere (Oxford) Vol. 57; no. 10; pp. 1245 - 1255
• Main Authors: Bracchini, Luca, Cózar, Andrés, Dattilo, Arduino M., Falcucci, Margherita, Gonzales, Rafael, Loiselle, Steven, Hull, Vincent
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01.12.2004; Elsevier
• Subjects: Brazil; CDOM; Chlorophyll - analysis; Earth sciences; Earth, ocean, space; Exact sciences and technology; Fresh Water - analysis; Geochemistry; Humic lake; Hydrology; Hydrology. Hydrogeology; Light; Mineralogy; Organic Chemicals - chemistry; Paraguay; Photochemistry; Regression Analysis; Silicates; Spectral extinction; Spectrophotometry; Ultraviolet Rays; Water geochemistry; Brazil; Paraguay; Bolivia, Santa Cruz, Puerto Suarez, Pantanal; CDOM; UV; Spectral extinction; Humic lake; South America; wetlands; suspended materials; optical properties; ultraviolet spectra; modern; hydrochemistry; lacustrine environment; photochemistry; dissolved materials; lakes
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2004.08.050

The extinction spectra in ultraviolet and visible radiation were analyzed using filtered and unfiltered water samples obtained in 11 open water bodies in the Ñeembucù (Paraguay) and Pantanal (Brazil) wetlands. The role of dissolved and suspended matter in the total extinction was analyzed between 260 nm and 700 nm. The chromophoric dissolved organic matter (CDOM) was the major component in extinction of considered ultraviolet radiation (260–400 nm). The differences in CDOM concentrations explained the main pattern of extinction of the ultraviolet radiation in the samples. Nevertheless, differences between the studied water bodies were found also to depend on the rate of photodegradation and photobleaching. The methodology developed in the present study was to distinguish “humic optic waters” according to quantity and quality of dissolved and suspended matter present. In the “humic optic water”, the penetration of 10% of incident UV radiation and the photoactive layer are estimated. The influence of particulate matter increases in the total extinction of the wavelengths higher than 400 nm. The integral of the extinction curve of suspended matter in the visible wavelengths (400–700 nm) was found to relate with the total suspended solids and chlorophyll concentrations.