Effective sulfur and energy recovery from hydrogen sulfide through incorporating an air-cathode fuel cell into chelated-iron process

• Published in: Journal of hazardous materials Vol. 263; pp. 643 - 649
• Main Authors: Sun, Min, Song, Wei, Zhai, Lin-Feng, Cui, Yu-Zhi
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 15.12.2013; Elsevier
• Subjects: Air; Air-cathode fuel cell; Anaerobiosis; Applied sciences; Bioelectric Energy Sources; Biofuels; Bioreactors; Chelate degradation; Chelated-iron process; Chelating; Chelating Agents - chemistry; Degradation; Edetic Acid - chemistry; Electricity; Electricity generation; Electrodes; Energy; Energy recovery; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cells; Gases; Hydrogen Sulfide - chemistry; Hydrogen-Ion Concentration; Iron; Iron - chemistry; Oxygen - chemistry; Pollution; Recovery; Sulfides - chemistry; Sulfur; Sulfur - chemistry; Sulfur recovery; Sulfur recovery; Chelate degradation; Air-cathode fuel cell; Chelated-iron process; Electricity generation; Catalyst regeneration; Energy recovery; Hydrogen sulfides; Biogas; EDTA; Iron III; Chelating agent; pH; Fuel cell
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2013.10.026

•Effective sulfur and energy recoveries from H2S in a novel chelated-iron process.•Air-cathode fuel cell was employed for the catalyst regeneration.•The problem of chelate degradation was well controlled.•This process maintained stable efficiency in the recycling operation.•Results in treating a H2S-containing biogas confirmed the feasibility of process. The chelated-iron process is among the most promising techniques for the hydrogen sulfide (H2S) removal due to its double advantage of waste minimization and resource recovery. However, this technology has encountered the problem of chelate degradation which made it difficult to ensure reliable and economical operation. This work aims to develop a novel fuel-cell-assisted chelated-iron process which employs an air-cathode fuel cell for the catalyst regeneration. By using such a process, sulfur and electricity were effectively recovered from H2S and the problem of chelate degradation was well controlled. Experiment on a synthetic sulfide solution showed the fuel-cell-assisted chelated-iron process could maintain high sulfur recovery efficiencies generally above 90.0%. The EDTA was preferable to NTA as the chelating agent for electricity generation, given the Coulombic efficiencies (CEs) of 17.8±0.5% to 75.1±0.5% for the EDTA-chelated process versus 9.6±0.8% to 51.1±2.7% for the NTA-chelated process in the pH range of 4.0–10.0. The Fe (III)/S2− ratio exhibited notable influence on the electricity generation, with the CEs improved by more than 25% as the Fe (III)/S2− molar ratio increased from 2.5:1 to 3.5:1. Application of this novel process in treating a H2S-containing biogas stream achieved 99% of H2S removal efficiency, 78% of sulfur recovery efficiency, and 78.6% of energy recovery efficiency, suggesting the fuel-cell-assisted chelated-iron process was effective to remove the H2S from gas streams with favorable sulfur and energy recovery efficiencies.