Crystal structure of tris-[4-(naphthalen-1-yl)phen-yl]amine

In the title mol-ecule, C H N, the central N atom shows no pyramidalization, so that the N atom and the three C atoms bound to the N atom lie almost in the same plane. The three -phenyl-ene rings bonded to the N atom are in a propeller form. All of the naphthalene ring systems are slightly bent. In...

Full description

Saved in:
Bibliographic Details
Published inActa crystallographica. Section E, Crystallographic communications Vol. 76; no. Pt 10; pp. 1649 - 1652
Main Authors Yano, Masafumi, Kashiwagi, Yukiyasu, Inada, Yoshinori, Hayashi, Yuki, Mitsudo, Koichi, Kubono, Koji
Format Journal Article
LanguageEnglish
Published England International Union of Crystallography 01.10.2020
Subjects
crystal structure
electroluminescence
hole transporter
organic electronics
Research Communications
triarylamine
crystal structure
hole transporter
tri­aryl­amine
organic electronics
electroluminescence
Online AccessGet full text

Cover

More Information
Summary:In the title mol-ecule, C H N, the central N atom shows no pyramidalization, so that the N atom and the three C atoms bound to the N atom lie almost in the same plane. The three -phenyl-ene rings bonded to the N atom are in a propeller form. All of the naphthalene ring systems are slightly bent. In the crystal, mol-ecules form an inversion dimer, through two pairs of C-H⋯ inter-actions, which further inter-acts with the adjacent dimer another two pairs of C-H⋯ inter-actions, forming a column structure along the axis. There are no significant inter-actions between these column structures.
ISSN:2056-9890
2056-9890
DOI:10.1107/s2056989020012529