Interaction of Diphenyltin(IV) Dichloride with Some Selected Bioligands
The interaction of diphenyltin(IV) with selected bioligands having a variety of model functional groups were investigated using the potentiometric technique. The hydrolysis constants of diphenyltin(IV) cation and the step-wise formation constants of the complexes formed in solution were calculated u...
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Published in | Chemical & pharmaceutical bulletin Vol. 49; no. 3; pp. 253 - 257 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
Tokyo
The Pharmaceutical Society of Japan
01.03.2001
Maruzen Japan Science and Technology Agency |
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Abstract | The interaction of diphenyltin(IV) with selected bioligands having a variety of model functional groups were investigated using the potentiometric technique. The hydrolysis constants of diphenyltin(IV) cation and the step-wise formation constants of the complexes formed in solution were calculated using the non linear least-squares program MINIQUAD-75. The participation of different ligand functional groups in binding to organotin is discussed. The concentration distribution of the various complex species was evaluated as a function of pH. |
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AbstractList | The interaction of diphenyltin(IV) with selected bioligands having a variety of model functional groups were investigated using the potentiometric technique. The hydrolysis constants of diphenyltin(IV) cation and the step-wise formation constants of the complexes formed in solution were calculated using the non linear least-squares program MINIQUAD-75. The participation of different ligand functional groups in binding to organotin is discussed. The concentration distribution of the various complex species was evaluated as a function of pH. |
Author | MOHAMED, Mahmoud Mohamed Ahmed SHOUKRY, Mohamed Mohamed |
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Cites_doi | 10.1139/v64-117 10.1002/aoc.590060103 10.1016/0162-0134(92)84053-P 10.1016/S0039-9140(96)02113-3 10.1021/ic00171a005 10.1016/S0022-0728(73)80379-1 10.1016/S0020-1693(97)06044-1 10.1007/978-3-642-74191-3_2 10.1080/00958979209409742 10.1016/S0020-1693(00)95610-X 10.1016/0039-9140(95)01708-9 10.1007/978-3-642-74191-3_5 |
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Keywords | Equilibrium constant Thiol Organic ligand Stability constant Penicillamine Sulfur containing aminoacid α-Aminoacid Tin IV Complexes Medium effect pH Chloro complex Aminothiol Tin Organic compounds |
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References_xml | – ident: 17 – volume: 42 start-page: 781 issn: 0008-4042 year: 1964 ident: 19 publication-title: Can. J. Chem. doi: 10.1139/v64-117 contributor: fullname: Tobias R.S., Yasuda M. – volume: 6 start-page: 3 year: 1992 ident: 4 publication-title: App. Organometallic Chem. doi: 10.1002/aoc.590060103 contributor: fullname: Tsangaris J.M., Williams D.R. – ident: 5 doi: 10.1016/0162-0134(92)84053-P – volume: 1989 start-page: 773 issn: 1472-7773 ident: 20 publication-title: J. Chem. Soc., Dalton Trans. contributor: fullname: Arena G., Purrello R., Rizzarelli E – ident: 10 doi: 10.1016/S0039-9140(96)02113-3 – volume: 23 start-page: 275 issn: 0020-1669 issue: 3 year: 1984 ident: 14 publication-title: Inorg. Chem. doi: 10.1021/ic00171a005 contributor: fullname: Motekaitis R.J., Martell A.E., Nels – ident: 1 – ident: 12 – volume: 48 start-page: 475 year: 1973 ident: 22 publication-title: J. Electroanal. Chem. doi: 10.1016/S0022-0728(73)80379-1 contributor: fullname: Farooq O., Ahmed N., Malik A.V. – volume: 22 start-page: 253 year: 1999 ident: 11 publication-title: Main Group Met. Chem. contributor: fullname: Al-Najjar A.A., Shehata M.R., Moham – ident: 18 doi: 10.1016/S0020-1693(97)06044-1 – volume: 20 start-page: 281 year: 1997 ident: 9 publication-title: Main Group Met. Chem. contributor: fullname: Shoukry M.M., Mohamed M.M.A. – ident: 3 doi: 10.1007/978-3-642-74191-3_2 – volume: 130 start-page: 177 year: 1993 ident: 7 publication-title: Bull. Soc. Chem. Fr. contributor: fullname: Shoukry M.M. – ident: 16 – volume: 25 start-page: 111 issn: 0095-8972 issue: 2 year: 1992 ident: 6 publication-title: J. Coord. Chem. doi: 10.1080/00958979209409742 – volume: 1981 start-page: 1377 issn: 0020-1669 ident: 23 publication-title: Inorg. Chem. contributor: fullname: Lim M.C. – ident: 15 doi: 10.1016/S0020-1693(00)95610-X – ident: 8 doi: 10.1016/0039-9140(95)01708-9 – volume: 1994 start-page: 2749 issn: 1472-7773 ident: 21 publication-title: J. Chem. Soc., Dalton Trans. contributor: fullname: Natsume T., Aizawa S.I., Hatano K. – ident: 2 doi: 10.1007/978-3-642-74191-3_5 – volume: 20 start-page: 252 issn: 0340-4285 issue: 3 year: 1995 ident: 13 publication-title: Transition Met. Chem. |
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SubjectTerms | Algorithms amino acid Chemical Phenomena Chemistry Chemistry, Physical dicarboxylic acid diphenyltin(IV) dichloride DNA constituent Drug Carriers - chemistry equilibrium study Exact sciences and technology Ge, sn, pb derivatives Hydrogen-Ion Concentration Indicators and Reagents Ligands Organic chemistry Organometalloidal and organometallic compounds Organotin Compounds - chemistry peptide Potentiometry Preparations and properties |
Title | Interaction of Diphenyltin(IV) Dichloride with Some Selected Bioligands |
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