Non-destructive inspection of food and technical oils by terahertz spectroscopy

• Published in: Scientific reports Vol. 8; no. 1; pp. 18025 - 11
• Main Authors: Karaliūnas, Mindaugas, Nasser, Kinan E, Urbanowicz, Andrzej, Kašalynas, Irmantas, Bražinskienė, Dalia, Asadauskas, Svajus, Valušis, Gintaras
• Format: Journal Article
• Language: English
• Published: England Nature Publishing Group 21.12.2018; Nature Publishing Group UK
• Subjects: Degradation products; Dietary Fats, Unsaturated - analysis; Drug Industry - methods; Drug Industry - standards; Drug Stability; Edible oils; Esters; Fats, Unsaturated - chemistry; Food Analysis - methods; Food Analysis - standards; Food industry; Oils - analysis; Oils - chemistry; Oleic acid; Optical Phenomena; Optical properties; Pharmaceutical industry; Pharmaceutical Preparations - analysis; Process controls; Quality Control; Refractometry; Spectroscopy; Spectrum analysis; Terahertz Spectroscopy - methods; Vegetable oils
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-018-36151-3

Quality control and non-destructive monitoring are of notable interest of food and pharmaceutical industries. It relies on the ability of non-invasive inspection which can be employed for manufacturing process control. We hereby apply terahertz (THz) time-domain spectroscopy as non-destructive technique to monitor pure and degraded oils as well as hydrocarbon chemicals. Significant differences in the spectra of refractive index (RI) and absorption coefficient arising from the presence of ester linkages in the edible and technical oils were obtained. Explicit increase from 1.38 to 1.5 of the RI in all THz spectrum range was observed in hydrocarbons and mono-functional esters with the increase of molar mass. This fact is in contrast of RI dependence on molar mass in multi-functional esters, such as Adipate or vegetable oils, where it is around 1.54. Degradation products, Oleic Acid (OA) and water in particular, lead only to some changes in absorption coefficient and RI spectra of vegetable oils. We demonstrate that complex colloidal and supramolecular processes, such as dynamics of inverse micelles and oil hydrolysis, take part during oil degradation and are responsible for non-uniform dependence of optical properties on extent of degradation.