Atom Efficient Preparation of Zinc Selenates for the Synthesis of Selenol Esters under "On Water" Conditions

We describe here an atom efficient procedure to prepare selenol esters in good to excellent yields by reacting [(PhSe)₂Zn] or [(PhSe)₂Zn]TMEDA with acyl chlorides under "on water" conditions. The method is applicable to a series of aromatic and aliphatic acyl chlorides and tolerates the pr...

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Published inMolecules (Basel, Switzerland) Vol. 22; no. 6; p. 953
Main Authors Sancineto, Luca, Pinto Vargas, Jaqueline, Monti, Bonifacio, Arca, Massimiliano, Lippolis, Vito, Perin, Gelson, Lenardao, Eder Joao, Santi, Claudio
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 08.06.2017
MDPI
Subjects
Aliphatic compounds
Carbon monoxide
Chlorides
Esters
Esters - chemical synthesis
Esters - chemistry
Hydration
Peptides
Reagents
Selenic Acid - chemistry
Selenium
Selenium Compounds - chemical synthesis
Selenium Compounds - chemistry
selenol esters
Solvents
Sulfur
TMEDA
water
Water - chemistry
Zinc
Zinc - chemistry
TMEDA
selenium
selenol esters
water
zinc
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Summary:We describe here an atom efficient procedure to prepare selenol esters in good to excellent yields by reacting [(PhSe)₂Zn] or [(PhSe)₂Zn]TMEDA with acyl chlorides under "on water" conditions. The method is applicable to a series of aromatic and aliphatic acyl chlorides and tolerates the presence of other functionalities in the starting material.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1420-3049
1420-3049
DOI:10.3390/molecules22060953