Perfluoropyridine: Discovery, Chemistry, and Applications in Polymers and Material Science

Perfluoropyridine (PFPy) is an organofluorine compound that has been employed for a variety of applications, from straightforward chemical synthesis to more advanced functions, such as fluorinated networks and polymers. This can be directly attributed to the highly reactive nature of PFPy, especiall...

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Published inMolecules (Basel, Switzerland) Vol. 27; no. 5; p. 1616
Main Authors Gautam, Ritesh, Geniza, Ian, Iacono, Scott T, Friesen, Chadron M, Jennings, Abby R
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 28.02.2022
MDPI
Subjects
Chemistry
Fluorides
Fluorination
Fluoropolymers
nucleophilic aromatic substitution
organofluorine
Organofluorine compounds
perfluoropyridine
Polymers
Review
Thermal analysis
Thermal utilization
perfluoropyridine
nucleophilic aromatic substitution
fluoropolymers
organofluorine
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Summary:Perfluoropyridine (PFPy) is an organofluorine compound that has been employed for a variety of applications, from straightforward chemical synthesis to more advanced functions, such as fluorinated networks and polymers. This can be directly attributed to the highly reactive nature of PFPy, especially towards nucleophilic aromatic substitution (SNAr). The aim of this review is to highlight the discovery and synthesis of PFPy, discuss its reactive nature towards SNAr, and to summarize known reports of the utilization and thermal analysis of PFPy containing fluoropolymers and fluorinated network materials.
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ISSN:1420-3049
1420-3049
DOI:10.3390/molecules27051616