Vibrational Property of α-Borophene Determined by Tip-Enhanced Raman Spectroscopy

• Published in: Molecules (Basel, Switzerland) Vol. 27; no. 3; p. 834
• Main Authors: Zhang, Ping, Tian, Xirui, Sheng, Shaoxiang, Ma, Chen, Chen, Linjie, Feng, Baojie, Cheng, Peng, Zhang, Yiqi, Chen, Lan, Zhao, Jin, Wu, Kehui
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 27.01.2022; MDPI
• Subjects: Boron; Borophene; Buckling; density functional theory calculations; Material properties; Polymorphism; Raman spectroscopy; Scanning tunneling microscopy; Silver; Spatial discrimination; Spatial resolution; Spectroscopy; Spectrum analysis; Symmetry; tip-enhanced Raman spectroscopy; vibrational modes; borophene; density functional theory calculations; vibrational modes; scanning tunneling microscopy; tip-enhanced Raman spectroscopy
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules27030834

We report a Raman characterization of the α borophene polymorph by scanning tunneling microscopy combined with tip-enhanced Raman spectroscopy. A series of Raman peaks were discovered, which can be well related with the phonon modes calculated based on an asymmetric buckled α structure. The unusual enhancement of high-frequency Raman peaks in TERS spectra of α borophene is found and associated with its unique buckling when landed on the Ag(111) surface. Our paper demonstrates the advantages of TERS, namely high spatial resolution and selective enhancement rule, in studying the local vibrational properties of materials in nanoscale.