Molecular Structure Modulated Trap Distribution and Carrier Migration in Fluorinated Epoxy Resin

• Published in: Molecules (Basel, Switzerland) Vol. 25; no. 13; p. 3071
• Main Authors: Li, Jin, Wang, Yufan, Ran, Zhaoyu, Yao, Hang, Du, Boxue, Takada, Tatsuo
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 06.07.2020; MDPI
• Subjects: Benzene - chemistry; Carrier mobility; Charging; Communication; Computer Simulation; Direct current; Electric fields; Electron distribution; Electrons; Energy; epoxy resin; Epoxy resins; Epoxy Resins - chemistry; Fluorination; Halogenation; Hot pressing; Insulators; Models, Molecular; Molecular orbitals; Molecular Structure; Polymers; quantum chemical calculation; Quantum Theory; Static Electricity; Surface charge; Transmission lines; trap distribution; molecular structure; surface charge; epoxy resin; quantum chemical calculation; trap distribution
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules25133071

Surface charge accumulation on epoxy insulators is one of the most serious problems threatening the operation safety of the direct current gas-insulated transmission line (GIL), and can be efficiently inhibited by the surface modification technology. This paper investigated the mechanisms of fluorination modulated surface charge behaviors of epoxy resin through quantum chemical calculation (QCC) analysis of the molecular structure. The results show that after fluorination, the surface charge dissipation process of the epoxy sample is accelerated by the introduced shallow trap sites, which is further clarified by the carrier mobility model. The electron distribution probability of the highest occupied molecular orbitals (HOMO) under positive charging and the lowest unoccupied molecular orbitals (LUMO) under negative charging shows distinctive patterns. It is illustrated that electrons are likely to aggregate locally around benzenes for the positively charged molecular structure, while electrons tend to distribute all along the epoxy chain under negatively charging. The calculated results verify that fluorination can modulate surface charge behaviors of epoxy resin through redesigning its molecular structure, trap distribution and charging patterns.