Comparative study of photocatalysis with bulk and nanosheet graphitic carbon nitrides enhanced with silver

• Published in: Scientific reports Vol. 14; no. 1; p. 11512
• Main Authors: Michalska, Monika, Pavlovsky, Jiri, Simha Martynkova, Grazyna, Kratosova, Gabriela, Hornok, Viktoria, Nagy, Peter B., Novak, Vlastimil, Szabo, Tamas
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 20.05.2024; Nature Publishing Group; Nature Portfolio
• Subjects: 639/166; 639/301; 639/301/299; 639/638; Acid orange 7; Ag nanoparticles; Carbon; Comparative studies; Dyes; g-C3N4; Graphitic carbon nitride; Humanities and Social Sciences; Low temperature; multidisciplinary; Nanoparticles; Photocatalysis; Photocatalytic degradation; Photodegradation; Reducing agents; Science; Science (multidisciplinary); Silver; Ultraviolet radiation; Wastewater treatment; Wavelengths; Acid orange 7; Photocatalytic degradation; Ag nanoparticles; g-C; N; Graphitic carbon nitride; g-C3N4
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-024-62291-w

The main goal of this research is to investigate the effectiveness of graphitic carbon nitride (g-C 3 N 4 , g-CN) in both bulk and nanosheet forms, which have been surface-modified with silver nanoparticles (Ag NPs), as photocatalysts for the degradation of acid orange 7 (AO7), a model dye. The photodegradation of AO7 dye molecules in water was used to test the potential photocatalytic properties of these powder materials under two different lamps with wavelengths of 368 nm (UV light) and 420 nm (VIS light). To produce Ag NPs (Ag content 0.5, 1.5, and 3 wt%) on the g-CN materials, a new synthesis route based on a wet and low-temperature method was proposed, eliminating the need for reducing agents. The photodegradation activity of the samples increased with increasing silver content, with the best photocatalytic performances achieved for bulk g-CN samples and nanosheet silver-modified samples (with the highest content of 3 wt% Ag) under UV light, i.e., more than 75% and 78%, respectively. The VIS-induced photocatalytic activity of both examined series was higher than that of UV. The highest activities of 92% and 98% were achieved for the 1.5% Ag-modified g-CN bulk and nanosheet materials. This research presents an innovative, affordable, and environmentally friendly chemical approach to synthesizing photocatalysts that can be used for degrading organic pollutants in wastewater treatment.