Muonium Addition to the Radicalic Carbon in 1,3-Diphosphacyclobutane-2,4-diyl

When a crystalline 1,3-diphosphacyclobutane-2,4-diyl bearing a 3,5-dichloro-2,4,6-triazine substituent was irradiated with muon beam, two paramagnetic species showing muon hyperfine coupling constants (hfcs) of 4.5 MHz and 6.5 MHz were produced via addition of muonium. These observed paramagnetic sp...

Full description

Saved in:
Bibliographic Details
Published inBulletin of the Chemical Society of Japan Vol. 94; no. 12; pp. 2970 - 2972
Main Authors Ito, Shigekazu, Akama, Hikaru, Ueta, Yasuhiro, McKenzie, Iain, Kojima, Kenji M
Format Journal Article
LanguageEnglish
Published The Chemical Society of Japan 15.12.2021
Subjects
Muon spin spectroscopy
Radicals
Phosphorus heterocycles
Online AccessGet full text

Cover

More Information
Summary:When a crystalline 1,3-diphosphacyclobutane-2,4-diyl bearing a 3,5-dichloro-2,4,6-triazine substituent was irradiated with muon beam, two paramagnetic species showing muon hyperfine coupling constants (hfcs) of 4.5 MHz and 6.5 MHz were produced via addition of muonium. These observed paramagnetic species are consistent with the cis and trans isomers of the C-muoniated 1,3-diphosphacyclobutane-2,4-diyl.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.20210352