Comparative Analysis of the Mechanical Behaviour of PEF and PET Uniaxial Stretching Based on the Time/Temperature Superposition Principle

• Published in: Polymers Vol. 13; no. 19; p. 3295
• Main Authors: Forestier, Emilie, Combeaud, Christelle, Guigo, Nathanael, Corvec, Guillaume, Pradille, Christophe, Sbirrazzuoli, Nicolas, Billon, Noelle
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.10.2021; MDPI
• Subjects: biobased thermoplastics; Crystallization; Engineering Sciences; Hydrocarbons; Investigations; Materials; Mechanical analysis; Mechanical properties; poly(ethylene 2,5-furandicarboxylate) (PEF); poly(ethylene terephthalate) (PET); Polyester resins; Polyethylene terephthalate; Polymers; Strain hardening; strain-induced crystallization; Stretching; Superposition (mathematics); time/temperature principle; uniaxial stretching; Switzerland
• ISSN: 2073-4360; 2073-4360
• DOI: 10.3390/polym13193295

Poly(ethylene 2,5-furandicarboxylate), PEF and poly(ethylene terephthalate), PET, are two polyesters with close chemical structures. It leads to similar thermal, mechanical and barrier properties. In order to optimize their stretching, a strategy based on the time/temperature principle is used. The building of master curves, in the linear visco-elastic domain, allows the identification of the experimental conditions for which the two materials are in the same physical state. The initial physical state of the materials is important as, to fit with the industrial constrains, the polymers must reach high level of deformation, and develop strain induced crystallization (SIC). In this paper, the screening of the forming range is described, as well as the mechanical response depending on the stretching settings. Moreover, the same mechanical response can exist for PEF and PET if the same gap from the α-relaxation exists.