Synthesis of a Dichlorodigermasilane: Double Si–Cl Activation by a Ge=Ge Unit

Halogenated oligosilanes and oligogermanes are interesting compounds in oligosilane chemistry from the viewpoint of silicon-based-materials. Herein, it was demonstrated that a 1,2-digermacyclobutadiene derivative could work as a bis-germylene building block towards double Si–Cl activation to give a...

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Published inInorganics Vol. 5; no. 4; p. 79
Main Authors Sugahara, Tomohiro, Tokitoh, Norihiro, Sasamori, Takahiro
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 14.11.2017
Subjects
Chemistry
digermacyclobutadiene
digermene
Germanium
germylene
Silicon
Si–Cl activation
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Summary:Halogenated oligosilanes and oligogermanes are interesting compounds in oligosilane chemistry from the viewpoint of silicon-based-materials. Herein, it was demonstrated that a 1,2-digermacyclobutadiene derivative could work as a bis-germylene building block towards double Si–Cl activation to give a halogenated oligometallane, a bis(chlorogermyl)dichlorosilane derivative.
ISSN:2304-6740
2304-6740
DOI:10.3390/inorganics5040079