Synthesis of a diamino substituted terphenyldivinyl chromophore

(E,E)-1,4-bis(4'-aminostyryl)-2,5-bis(octyloxy)-benzene (6) and its derivative (E,E)-1,4-bis(4'-acetamidostyryl)-2,5-bis(octyloxy)-benzene (7) were synthesized and characterized after alkylation, bromomethylation, Horner-Emmons reaction and reduction from hydroquinone. In order to gain mor...

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Published inMolecules (Basel, Switzerland) Vol. 14; no. 6; pp. 2111 - 2117
Main Authors Du, Zhen-Ting, Liu, Ru, Wang, Jun-Ru, Li, An-Pai
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 10.06.2009
Molecular Diversity Preservation International
Subjects
Bisphosphonates
chromophore
energy transfer
Hydrocarbons
Molecular Structure
Perylene - chemistry
Photosynthesis
Polymers - chemical synthesis
Polymers - chemistry
synthesis
terphenyldivinyl
Vinyl Compounds - chemistry
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Summary:(E,E)-1,4-bis(4'-aminostyryl)-2,5-bis(octyloxy)-benzene (6) and its derivative (E,E)-1,4-bis(4'-acetamidostyryl)-2,5-bis(octyloxy)-benzene (7) were synthesized and characterized after alkylation, bromomethylation, Horner-Emmons reaction and reduction from hydroquinone. In order to gain more molecular electronic data, HOMO and LUMO of compound 6 have been calculated by Gaussian 03 W.
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ISSN:1420-3049
1420-3049
DOI:10.3390/molecules14062111