Poly[bis-(acetonitrile-κN)bis-[μ(3)-bis(tri-fluoro-methane-sulfonyl)-imido-κO,O':O'':O''']dilithium]

In the title compound, [Li(2)(CF(3)SO(2)NSO(2)CF(3))(2)(CH(3)CN)(2)](n), two Li(+) cations reside on crystallographic inversion centers, each coordinated by six O atoms from bis(trifluoromethanesulfonyl)imide (TFSI(-)) anions. The third Li(+) cation on a general position is four-coordinated by two a...

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Published inActa crystallographica. Section E, Structure reports online Vol. 67; no. Pt 5; p. m534
Main Authors Seo, Daniel M, Boyle, Paul D, Henderson, Wesley A
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 01.05.2011
Subjects
BASIC BIOLOGICAL SCIENCES
Crystallography
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Metal-Organic Papers
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Summary:In the title compound, [Li(2)(CF(3)SO(2)NSO(2)CF(3))(2)(CH(3)CN)(2)](n), two Li(+) cations reside on crystallographic inversion centers, each coordinated by six O atoms from bis(trifluoromethanesulfonyl)imide (TFSI(-)) anions. The third Li(+) cation on a general position is four-coordinated by two anion O atoms and two N atoms from acetonitrile mol-ecules in a tetra-hedral geometry.
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content type line 23
SC0002169
USDOE Office of Science (SC)
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536811011561