A Convoluted Polymeric Imidazole Palladium Catalyst: Structural Elucidation and Investigation of the Driving Force for the Efficient Mizoroki-Heck Reaction
MPPI‐Pd (7 mol ppm Pd), prepared from poly(N‐isopropylacrylamide‐co‐N‐vinylimidazole) and (NH4)2PdCl4 by our molecular convolution method, promoted the Mizoroki–Heck reaction in water to give the corresponding coupling products with high yield and reusability. To clarify why the catalyst was so acti...
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Published in | ChemCatChem Vol. 7; no. 14; pp. 2141 - 2148 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag
13.07.2015
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
Subjects | |
Online Access | Get full text |
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Summary: | MPPI‐Pd (7 mol ppm Pd), prepared from poly(N‐isopropylacrylamide‐co‐N‐vinylimidazole) and (NH4)2PdCl4 by our molecular convolution method, promoted the Mizoroki–Heck reaction in water to give the corresponding coupling products with high yield and reusability. To clarify why the catalyst was so active, structural elucidation and temperature‐dependent absorption/discharge investigation were performed using X‐ray absorption fine structure analysis, Raman and far‐IR spectroscopy, elemental analysis, and DFT calculations, which provided the structure of cis‐PdCl2L2 (L=imidazole moiety). Moreover, the temperature‐dependent absorption and discharge of aryl iodides and water in MPPI‐Pd were observed with near‐IR spectroscopy and macroscopic observations. The efficient diffusion of organic substrates into the internal nanospaces in MPPI‐Pd and the following discharge of the water molecules at 80 °C should enhance the catalytic activity dramatically as the driving force of the reaction.
Pd polymer provides products: MPPI‐Pd, prepared from poly(N‐isopropylacrylamide‐co‐N‐vinylimidazole) and (NH4)2PdCl4 by our molecular convolution method, promotes the Mizoroki–Heck reaction in water to give the corresponding coupling products with high yield and reusability. |
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Bibliography: | JST ACT-C Naito Foundation istex:62DC03F05720C1097A65F72E3C8BFF5443B63C9C JST CREST ArticleID:CCTC201500249 Takeda Science Foundation RIKEN JSPS - No. 24550126; No. 20655035; No. 2105 ark:/67375/WNG-QSG1GTV3-0 |
ISSN: | 1867-3880 1867-3899 |
DOI: | 10.1002/cctc.201500249 |