Weakly Coordinating Directing Groups for Ruthenium(II)- Catalyzed CH Activation

Synthetically useful functional groups, including ketones, amides, carbamates, carboxylic acids, aldehydes or ethers, have been identified as weakly coordinating directing groups in efficient ruthenium(II)‐catalyzed CH functionalizations. This strategy set the stage for versatile CH bond olefinati...

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Bibliographic Details
Published inAdvanced synthesis & catalysis Vol. 356; no. 7; pp. 1461 - 1479
Main Authors De Sarkar, Suman, Liu, Weiping, Kozhushkov, Sergei I., Ackermann, Lutz
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 05.05.2014
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
Activation
Aldehydes
Alkynes
Amides
Aromatic compounds
Carbamates (tradename)
Carboxylic acids
CH activation
directing groups
Ethers
Functional groups
homogenous catalysis
Hydrogen bonds
Ketones
Organic chemistry
Oxygenation
Ruthenium
Ruthenium compounds
weak coordination
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Summary:Synthetically useful functional groups, including ketones, amides, carbamates, carboxylic acids, aldehydes or ethers, have been identified as weakly coordinating directing groups in efficient ruthenium(II)‐catalyzed CH functionalizations. This strategy set the stage for versatile CH bond olefinations, oxygenations, nitrogenations and oxidative alkyne annulations among others. Thereby, step‐economical access to diversely decorated arenes and heteroarenes was provided in a sustainable fashion.
Bibliography:European Research Council under the European Community 7th Framework Program
Fonds der Chemischen Industrie
ArticleID:ADSC201400110
Chinese Scholarship Council
Alexander-von-Humboldt Foundation
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SourceType-Scholarly Journals-1
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ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201400110