Nanoscale redox mapping at the MoS2-liquid interface
Layered MoS 2 is considered as one of the most promising two-dimensional photocatalytic materials for hydrogen evolution and water splitting; however, the electronic structure at the MoS 2 -liquid interface is so far insufficiently resolved. Measuring and understanding the band offset at the surface...
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Published in | Nature communications Vol. 12; no. 1; p. 1321 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
London
Nature Publishing Group UK
26.02.2021
Nature Portfolio |
Subjects | |
Online Access | Get full text |
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Summary: | Layered MoS
2
is considered as one of the most promising two-dimensional photocatalytic materials for hydrogen evolution and water splitting; however, the electronic structure at the MoS
2
-liquid interface is so far insufficiently resolved. Measuring and understanding the band offset at the surfaces of MoS
2
are crucial for understanding catalytic reactions and to achieve further improvements in performance. Herein, the heterogeneous charge transfer behavior of MoS
2
flakes of various layer numbers and sizes is addressed with high spatial resolution in organic solutions using the ferrocene/ferrocenium (Fc/Fc
+
) redox pair as a probe in near-field scanning electrochemical microscopy, i.e. in close nm probe-sample proximity. Redox mapping reveals an area and layer dependent reactivity for MoS
2
with a detailed insight into the local processes as band offset and confinement of the faradaic current obtained. In combination with additional characterization methods, we deduce a band alignment occurring at the liquid-solid interface.
Here, high-resolution atomic force microscopy and scanning electrochemical microscopy are used to investigate the electron transfer behaviour of layered MoS
2
flakes in organic solutions, offering insights on the electronic band alignment at the solid-liquid interface. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 2041-1723 2041-1723 |
DOI: | 10.1038/s41467-021-21660-z |