Enhancing the SCC Resistance of the Anchor Steel with Microalloying in a Simulated Mine Environment

• Published in: Materials Vol. 16; no. 17; p. 5965
• Main Authors: Du, Hailong, An, Na, Wang, Xiyan, Li, Yongliang, Liu, Zhiyong, Jin, Aibing, Yang, Renshu, Pan, Yue, Li, Xiaogang
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 31.08.2023; MDPI
• Subjects: Anodic dissolution; Antimony; Chemical reactions; Coal mining; Copper; Corrosion; Corrosion effects; Corrosion resistance; Corrosion resistant steels; Crack initiation; Dissolution; Electrochemical reactions; Electrodes; High strength low alloy steels; Hot rolling; Hydrogen; Hydrogen embrittlement; Mechanical properties; Microalloying; Mineral industry; Mines; mining anchor bolts; Mining industry; Nickel; Niobium; SCC; Slow strain rate; Solution strengthening; Steel; Stress corrosion cracking; Synergistic effect; Tensile strength; Canada; China; United States > US
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma16175965

This work explored a new idea for enhancing the resistance to stress corrosion cracking (SCC) of mining anchor steel through microalloying. Microalloyed anchor steels with Nb, Cu, Ni, Sb, and C were prepared through vacuum smelting and hot rolling. Electrochemical measurements, slow strain rate tensile (SSRT) tests, and fracture morphology observations were used to study the electrochemical and SCC behavior in the simulated mine environment. The results proved that the microstructure of microalloyed steels varies slightly. Adding Ni, Cu, and Sb can improve the mechanical properties of the anchor steel, while reducing C content decreases tensile strength as a result of loss of the solution-strengthening effect. The addition of Sb, Cu, Ni, and reducing the content of C enhances the resistance to corrosion and SCC by mitigating anodic dissolution (AD), while adding Nb improves SCC resistance by inhibiting hydrogen embrittlement (HE). The combined addition of 1% Ni, 0.5% Cu, 0.05% Nb, 0.1% Sb, and 0.5% C presented the highest SCC resistance, which is a promising prospect for the development of high-performance, low-alloy anchor steels. The combined addition of 1% Ni, 0.5% Cu, 0.05% Nb, and 0.1% Sb resulted in the inhibition of electrochemical reactions and corrosion. As a result of the synergistic effect of the microalloy, both AD and HE mechanisms were simultaneously inhibited, which greatly enhanced SCC resistance.