Anion Exchange Membranes for Alkaline Polymer Electrolyte Fuel Cells—A Concise Review

• Published in: Materials Vol. 15; no. 16; p. 5601
• Main Authors: Kuppusamy, Hari Gopi, Dhanasekaran, Prabhakaran, Nagaraju, Niluroutu, Neeshma, Maniprakundil, Dass, Baskaran Mohan, Dhavale, Vishal M., Unni, Sreekuttan M., Bhat, Santoshkumar D.
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.08.2022; MDPI
• Subjects: anion exchange membrane; Anion exchanging; Cations; Chitosan; Conductivity; durability; Efficiency; Electrodes; Electrolytes; Electrolytic cells; Energy minerals; Force and energy; Fossil fuels; fuel cell; Fuel cell industry; Fuel cells; Interpenetrating networks; Ions; Membranes; Polymer industry; polymer membrane; Polymers; Polyvinyl alcohol; Proton exchange membrane fuel cells; Review; Separators; synthesis route; Thermal stability
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma15165601

Solid anion exchange membrane (AEM) electrolytes are an essential commodity considering their importance as separators in alkaline polymer electrolyte fuel cells (APEFC). Mechanical and thermal stability are distinguished by polymer matrix characteristics, whereas anion exchange capacity, transport number, and conductivities are governed by the anionic group. The physico-chemical stability is regulated mostly by the polymer matrix and, to a lesser extent, the cationic head framework. The quaternary ammonium (QA), phosphonium, guanidinium, benzimidazolium, pyrrolidinium, and spirocyclic cation-based AEMs are widely studied in the literature. In addition, ion solvating blends, hybrids, and interpenetrating networks still hold prominence in terms of membrane stability. To realize and enhance the performance of an alkaline polymer electrolyte fuel cell (APEFC), it is also necessary to understand the transport processes for the hydroxyl (OH−) ion in anion exchange membranes. In the present review, the radiation grafting of the monomer and chemical modification to introduce cationic charges/moiety are emphasized. In follow-up, the recent advances in the synthesis of anion exchange membranes from poly(phenylene oxide) via chloromethylation and quaternization, and from aliphatic polymers such as poly(vinyl alcohol) and chitosan via direct quaternization are highlighted. Overall, this review concisely provides an in-depth analysis of recent advances in anion exchange membrane (AEM) and its viability in APEFC.