Processing technologies for poly(lactic acid)

• Published in: Progress in polymer science Vol. 33; no. 8; pp. 820 - 852
• Main Authors: Lim, L.-T., Auras, R., Rubino, M.
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01.08.2008; Elsevier Science
• Subjects: Applied sciences; Converting; Exact sciences and technology; Organic polymers; Physicochemistry of polymers; PLA; Poly(lactic acid); Polylactide; Processing; Properties and characterization; Review; PP; BD; PS; Δ H c; PLA; BDI; PHA; PDLLA; η 0; Review; LDPE; OPP; PVT; Processing; HDPE; MFI; Poly(lactic acid); OPS; PDI; PLLA; DSC; PHO; ISBM; MD; Δ H rel; MDO; M n; T g; BUR; TDO; T m; HIPS; M w; HMDI; WAXS; TD; Δ H m; OPLA; PEG; Converting; MMT; WVTR; Polylactide; PET; Thermoforming; Crystallization; Thermal properties; Lactic acid polymer; Foaming process; Injection molding; Extrusion; Spinning; Blow molding; Thermal degradation; Rheological properties
• ISSN: 0079-6700; 1873-1619
• DOI: 10.1016/j.progpolymsci.2008.05.004

Poly(lactic acid) (PLA) is an aliphatic polyester made up of lactic acid (2-hydroxy propionic acid) building blocks. It is also a biodegradable and compostable thermoplastic derived from renewable plant sources, such as starch and sugar. Historically, the uses of PLA have been mainly limited to biomedical areas due to its bioabsorbable characteristics. Over the past decade, the discovery of new polymerization routes which allow the economical production of high molecular weight PLA, along with the elevated environmental awareness of the general public, have resulted in an expanded use of PLA for consumer goods and packaging applications. Because PLA is compostable and derived from renewable sources, it has been considered as one of the solutions to alleviate solid waste disposal problems and to lessen the dependence on petroleum-based plastics for packaging materials. Although PLA can be processed on standard converting equipment with minimal modifications, its unique material properties must be taken into consideration in order to optimize the conversion of PLA to molded parts, films, foams, and fibers. In this article, structural, thermal, crystallization, and rheological properties of PLA are reviewed in relation to its converting processes. Specific process technologies discussed are extrusion, injection molding, injection stretch blow molding, casting, blown film, thermoforming, foaming, blending, fiber spinning, and compounding.