Comparison of monolithic approaches for enantioselective capillary electrochromatography involving cyclodextrins
The access to CD‐modified monoliths for enantiomeric separation by CEC can be divided into two main approaches. (i) Silica‐based monoliths, prepared by either a sol–gel process or by sintering of silica particles, are modified after fabrication by coating with a CD selector. Alternatively the fusion...
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Published in | Journal of separation science Vol. 29; no. 10; pp. 1344 - 1352 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag
01.07.2006
WILEY‐VCH Verlag |
Subjects | |
Online Access | Get full text |
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Summary: | The access to CD‐modified monoliths for enantiomeric separation by CEC can be divided into two main approaches. (i) Silica‐based monoliths, prepared by either a sol–gel process or by sintering of silica particles, are modified after fabrication by coating with a CD selector. Alternatively the fusion of CD functionalized silica particle via gluing is feasible. (ii) Rigid or homogeneous organic polymer‐based monoliths, prepared by polymerization of organic monomers in the presence of a porogen, are modified with the CD selector either by copolymerization or by physical incorporation into the continuous bed. |
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Bibliography: | ArticleID:JSSC200600114 istex:FD5D6395C98598449DA3CE63CDDA3219172D6492 ark:/67375/WNG-D2G31WWV-J ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1615-9306 1615-9314 |
DOI: | 10.1002/jssc.200600114 |