Synthesis and the Crystal Structure of a New Chiral 1D Metal-Organic Coordination Polymer Based on L-Prolineamide-Substituted Diarylacetylenedicarboxylic Acid Derivative

• Published in: Molecules (Basel, Switzerland) Vol. 27; no. 23; p. 8376
• Main Authors: Veselovsky, Vladimir V, Isaeva, Vera I, Nissenbaum, Vera D, Kustov, Leonid M, Chernyshev, Vladimir V
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 30.11.2022; MDPI
• Subjects: Acids; Benzoic acid; Catalytic activity; Chemical properties; chiral diarylacetylenedicarboxylic acid derivative; Coordination polymers; Copper - chemistry; Crystal structure; Crystals; Enantiomers; homochiral metal–organic coordination polymer; Hydrocarbons; Hydrogen; Ligands; Metals; Molecular Structure; Morphology; Nitromethane; Polymer industry; Polymers; Polymers - chemistry; powder X-ray diffraction; Structure; Symmetry; Temperature; X ray powder diffraction; X-Ray Diffraction; Russia; homochiral metal–organic coordination polymer; chiral diarylacetylenedicarboxylic acid derivative; powder X-ray diffraction
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules27238376

The new homochiral 1D metal-organic coordination polymer [ was synthesized starting from the original 3,3'-ethyne-1,2-diylbis[6-(L-prolylamino)benzoic acid] (H EDPB). The unique crystal structure of the new compound was established by powder X-ray diffraction. The [ system shows catalytic activity and enantioselectivity in a Henry reaction of -nitrobenzaldehyde with nitromethane.