Cu K-Edge EXAFS Characterisation of Copper(I) Arenethiolate Complexes in both the Solid and Liquid State: Detection of CuCu Coordination

• Published in: Chemistry : a European journal Vol. 8; no. 24; pp. 5667 - 5678
• Main Authors: Tromp, Moniek, van Bokhoven, Jeroen A., Arink, Anne M., Bitter, Johannes H., van Koten, Gerard, Koningsberger, Diederik C.
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 16.12.2002; WILEY‐VCH Verlag
• Subjects: catalysts; copper; CC coupling; EXAFS data analysis; EXAFS spectroscopy
• ISSN: 0947-6539; 1521-3765
• DOI: 10.1002/1521-3765(20021216)8:24<5667::AID-CHEM5667>3.0.CO;2-O

Herein we describe a structural characterisation with EXAFS of copper(I) arenethiolate complexes in both the solid and liquid state. Previously noted difficulties in the detection of the CuCu interaction have been attributed to anti‐phase behaviour of different CuCu neighbour contributions. A data analysis procedure solely based on EXAFS parameters is presented which resolves these problems. A careful analysis of the individual coordination shells and the use of different k‐weightings during the data analysis are shown to be an absolute necessity to obtain reliable results. During R‐space fitting, the difference file technique is used to separate, examine and compare the individual contributions. Using this technique their statistical significance and correctness can be determined. Anti‐phase behaviour can be detected and accounted for in this way. An additional mixed organocopper aggregate [Cu4(SAr)2(Mes)2] with different Cu sites is analysed, which proves the value of the analysis procedure described above. Moreover, this newly developed EXAFS data analysis procedure is applicable to any other EXAFS spectrum obtained. The structural analysis of these organocopper complexes with EXAFS provides information about their actual structure and dynamic behaviour in solution. The technique can now be used to obtain insights into the reactivity of these complexes and the way in which they form catalytic reaction intermediates. A new data analysis procedure solely based on EXAFS parameters is presented which resolves difficulties in Cu K‐edge EXAFS data analysis that are attributed to anti‐phase behaviour of different contributions (see Figure). The described procedure has been applied to Cu K‐edge EXAFS spectra of different copper(I) complexes in both the solid state and solution. Application of this technique can give insights into the formation and reactivity of homogeneous complexes.