Deuterium isotope separation by combined electrolysis fuel cell

• Published in: Energy (Oxford) Vol. 149; pp. 98 - 104
• Main Authors: Ogawa, Ryota, Tanii, Risako, Dawson, Richard, Matsushima, Hisayoshi, Ueda, Mikito
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 15.04.2018; Elsevier BV
• Subjects: Alkaline water; Alkalinity; Catalysis; Catalytic activity; Deuterium; Dilution; Electrolysis; Electrolytes; Electrolytic cells; Energy; Energy efficiency; Fuel cell; Fuel cells; Fuel technology; Hydrogen evolution reactions; Isotope separation; Isotopes; Power loss; Proton exchange membrane fuel cells; Void fraction; Void fraction; Energy efficiency; Electrolysis; Fuel cell
• ISSN: 0360-5442; 1873-6785
• DOI: 10.1016/j.energy.2018.02.014

The framework about combined electrolysis fuel cell (CEFC) was reported previously [H. Matsushima et al., Energy, 2005; 30; 2413]. The purpose of the present study focused on measuring the separation factor and the energy reduction by assembling CEFC system. The separation of deuterium was studied with a 1-M KOH electrolyte containing 10 at% deuterium. Polarization plots of alkaline water electrolysis (AWE) revealed relationships between the catalytic activity of the hydrogen evolution reaction and the deuterium separation factor. The power loss was mainly attributed to gas bubble evolution. For polymer electrolyte fuel cells (PEFCs) with a Pt catalyst, approximately 21% of the electrical energy could be recovered by reusing hydrogen gas produced by the AWE. Furthermore, the PEFC could efficiently dilute protium in the gas phase, resulting in a high separation factor of 30.2 for the CEFC. •Water electrolysis and polymer electrolyte fuel cell can separate hydrogen isotopes.•The fuel cell reduced electric power consumption by approximately 21%.•High separation factor was achieved by water electrolysis combined with a fuel cell.