Mechanism study of aging oil demulsification and dehydration under ultrasonic irradiation

• Published in: Ultrasonics sonochemistry Vol. 105; p. 106859
• Main Authors: Gao, Jinbiao, Zhu, Jianjian, Gao, Qinghe, Zhao, Xiaoqing, Yu, Lanlan, Zhao, Jian, Jia, Fangchao, Wu, Yunlong, Li, Limin, Guo, Jiashuai
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 01.05.2024; Elsevier
• Subjects: Acoustic cavitation; Aging oil; Dehydration; Demulsification; Mechanism; Ultrasound; Dehydration; Acoustic cavitation; Ultrasound; Aging oil; Mechanism; Demulsification
• ISSN: 1350-4177; 1873-2828
• DOI: 10.1016/j.ultsonch.2024.106859

•The aging oil could also be dehydrated in the presence of ultrasonic cavitation.•The demulsification and emulsification of aging oil may be simultaneous during ultrasonic irradiation.•The mechanism of dehydration reduction of aging oil was revealed from the view of acoustic cavitation. With the tertiary oil recovery in the oilfield, the content of aging oil emulsion with high water content and complex components has become more prevalent, so it is crucial for aging oil to break the emulsification. In this paper, the experimental laws of water content are explored under the conditions of different transducer input powers through the ultrasonic reforming of aging oil, and the microscopic topography, particle size, components, etc. of oil samples before and after the irradiation of ultrasound are characterized through the microscopic analysis, particle size analysis and component analysis and other ways. The results show that the oil samples achieve the effect of demulsification and dehydration in the presence of ultrasonic cavitation effect, with a maximum dehydration rate of 98.24 %, and that the dehydration rate follows an “M−type” trend with the increase of power. The results of microscopic and particle size analyses demonstrate that ultrasonic irradiation destabilizes the oil–water interfacial membrane, and causes droplets of different sizes to collide, agglomerate, and settle. It was also observed that the droplets of the emulsion system are more evenly distributed and the intervals are increased. Furthermore, we hypothesize that ultrasound may be less irreversible in demulsification and dehydration of aging oil.